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Journal of Structural Chemistry

, Volume 59, Issue 8, pp 1944–1951 | Cite as

A Mercury(II) Mixed-Ligand Coordination Polymer Constructed from 4,7-Diphenyl- 1,10-Phenanthroline and Thiocyanate Ligands: Crystal Structure Studies, Spectroscopic Charactrization, And Thermal Analyses

  • V. AmaniEmail author
  • R. Alizadeh
  • A. Khosrojerdy
Article
  • 7 Downloads

Abstract

A new mixed-ligand coordination polymer [Hg(Ph2phen)(μ1,3-SCN)(SCN)]n (1) is prepared from Hg(SCN)2 and 4,7-diphenyl-1,10-phenanthroline (Ph2phen) in methanol. Suitable crystals for the X-ray diffraction measurement are obtained by methanol diffusion into a DMSO solution. Complex 1 is characterized by spectral methods (IR, UV-Vis, 13C{1H}NMR, 1H NMR, and luminescence), elemental analysis (CHNS), thermal analysis (TG, DTA), and single crystal X-ray diffraction. The structure of 1 is based on onedimensional zigzag chains running along the c axis. The luminescence spectrum shows stronger emission than that of free 4,7-diphenyl-1,10-phenanthroline.

Keywords

crystal structure mercury(II) complex 4,7-diphenyl-1,10-phenanthroline thermal gravimetric analysis differential thermal analysis luminescence spectroscopy 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Department of ChemistryFarhangian UniversityTehranIran
  2. 2.Damghan UniversitySchool of ChemistryDamghanIran

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