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Journal of Structural Chemistry

, Volume 59, Issue 8, pp 1935–1943 | Cite as

Synthesis Characterization, Crystal Structure, and Fluorescence of a New Samarium Schiff Base Complex

  • A. A. Abu-Yamin
  • M. A. AlDamenEmail author
  • M. O. Sinnokrot
  • H. K. Juwhari
  • M. Salman
  • I. Sarairah
  • J. Al-Hawarin
  • M. S. Mubarak
Article
  • 7 Downloads

Abstract

A new samarium Schiff base complex with the formula [SmIII(NO3)3(H2O)L2].EtOH, where L = {(E)-2- (((4-(ethoxycarbonyl)phenyl)iminio)-methyl)phenolate}, is synthesized. Its molecular structure is determined by means of single crystal X-ray diffraction (XRD). The complex crystallizes in the orthorhombic space group Pbca with the following unit cell dimensions: a = 14.1304(19) Å, b = 18.0218(13) Å, and c = 31.246(2) Å. Photoluminescence characteristics of the complex are investigated experimentally in the solid state and obtained theoretically using the Sparkle/PM7 modeling. Moreover, several methods such as powder XRD, FT-IR and UV-Visible spectroscopy are utilized to confirm the structure of the complex.

Keywords

samarium Schiff base fluorescence crystal structure Sparkle/PM7 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Abu-Yamin
    • 1
  • M. A. AlDamen
    • 2
    Email author
  • M. O. Sinnokrot
    • 3
  • H. K. Juwhari
    • 4
  • M. Salman
    • 1
  • I. Sarairah
    • 1
  • J. Al-Hawarin
    • 1
  • M. S. Mubarak
    • 2
  1. 1.Department of Chemistry, Faculty of ScienceAl-Hussien Bin Talal UniversityMa’anJordan
  2. 2.School of ChemistryUniversity of JordanAmmanJordan
  3. 3.Department of Chemistry, College of Arts and SciencesPetroleum InstituteAbu DhabiUAE
  4. 4.School of PhysicsUniversity of JordanAmmanJordan

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