Advertisement

Journal of Structural Chemistry

, Volume 59, Issue 7, pp 1678–1683 | Cite as

Synthesis and Crystal Structures of Two Coordination Polymers Based on a New N-Donor Aromatic Ligand

  • D. ZhaoEmail author
  • F. X. Ma
  • R. H. Zhang
Article
  • 8 Downloads

Abstract

Two new coordination polymers Co(C9H7N7)(SO4)(H2O) (I) and Cd(C9H6N7)2·H2O (II), where C9H7N7 is 4-(5-(1H-1,2,4-triazol-1-ylmethyl)-1,2,4-triazol-3-yl)pyridine, are synthesized through hydrothermal reactions and structurally determined by single-crystal X-ray diffraction analyses. The results reveal that compound I belongs to the triclinic space group P-1 with a 1-D chain structure, whereas compound II belongs to the monoclinic space group C2 with a 2D layer structure. Hydrogen bonds play an important role in the construction of 3D structure of the two compounds.

Keywords

hydrothermal coordination polymer X-ray diffraction layer structure hydrogen bond 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Y. M. Li, C. Y. Xiao, et al. Russ. J. Coord. Chem., 2013, 39(3), 293–296.CrossRefGoogle Scholar
  2. 2.
    P. Bourosh, O. Bologa, V. Shafranski, et al. Russ. J. Coord. Chem., 2014, 40(12), 891–903.CrossRefGoogle Scholar
  3. 3.
    W.-T. Chen, J.-W. Wen, Z.-G. Luo, et al. Synth. React. Inorg. Met.-Org. Chem., 2014, 44(10), 1464–1468.CrossRefGoogle Scholar
  4. 4.
    X.-L. Wang, J.-J. Cao, G.-C. Liu, et al. CrystEngComm, 2014, 16, 5732–5740.CrossRefGoogle Scholar
  5. 5.
    Bruker. APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA, 2013.Google Scholar
  6. 6.
    G. M. Sheldrick. Acta Crystallogr. A, 2008, 64(12), 112–122.CrossRefGoogle Scholar
  7. 7.
    A. L. Spek. J. Appl. Crystallogr., 2003, 36, 7–13.CrossRefGoogle Scholar
  8. 8.
    T. Glowiak and K. Kurdziel. J. Mol. Struct., 2000, 516, 1–5.CrossRefGoogle Scholar
  9. 9.
    I. D. Brown and D. Altermatt. Acta Crystallogr. B, 1985, 41, 244–247.CrossRefGoogle Scholar
  10. 10.
    M. Wicholas, A. D. Garrett, M. Gleaves, et al. Inorg. Chem., 2006, 45, 5804–5811.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringHenan Polytechnic UniversityJiaozuoP. R. China

Personalised recommendations