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Journal of Structural Chemistry

, Volume 59, Issue 3, pp 627–634 | Cite as

Study of Acidic (Tetracaprolactam) Dodecamolybdosilicate of the Composition (C6H11NO)4.5Н4[SiМо12O40]

  • A. F. Stepnova
  • G. Z. Kaziev
  • P. V. Dorovatovskii
  • Ya. V. Zubavichus
  • Saúl Holguín Quiñones
  • Nguen Van Bang
  • V. N. Khrustalev
Article
  • 11 Downloads

Abstract

New caprolactam dodecamolybdosilicate of the composition (C6H11NO)4.5Н4[SiМо12O40] (I) is synthesized. Chemical and crystallographic analyses, NMR and IR spectroscopic studies are performed. Compound I is found to crystallize in the monoclinic system with the space group P21/n. Unit cell parameters are: a = 19.945(4) Å, b = 13.340(3) Å, c = 28.110(6) Å, β = 110.75(3)°, ρcalc = 2.232 g/cm3, М = 2350.63, Z = 4, V = 6994(3) Å3.

Keywords

synthesis heteropolycompound polyoxometallates caprolactam structural analysis 

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References

  1. 1.
    M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer, New York (1983).CrossRefGoogle Scholar
  2. 2.
    E. A. Nikitina. Heteropolycompounds [in Russian], Goskhimizdat, Moscow (1962).Google Scholar
  3. 3.
    A. Dolbecq. Chem. Rev., 2010, 110, 6009–6048.CrossRefGoogle Scholar
  4. 4.
    K. C. Dey and V. Sharma. Intern. J. Chem. Tech. Res., 2010, 2(1), 368–375.Google Scholar
  5. 5.
    O. N. Sil`chenkova. Kinet. Katal., 2014, 55(1), 107–114.Google Scholar
  6. 6.
    A. Flutsch. Bioorg. Med. Chem. Lett., 2011, (21), 1162–1166.CrossRefGoogle Scholar
  7. 7.
    V. V. Pushkarev and A. F. Nikiforov. Radionuclide sorption by heteropolyacid salts [in Russian], Energoatomizdat, Moscow, 1982.Google Scholar
  8. 8.
    M. Yu. Sennikov. Physicochemical properties of polymer-salt compositions based on polyvinyl alcoho, polyvinylpyrrolidone and oxygen-containing Mo, W, and V salts [in Russian]. Diss. … Cand. Chem. Sc. Ekaterinburg, 2007.Google Scholar
  9. 9.
    S. Ivanova. ISRN Chem. Engin., 2014, (2014),13.CrossRefGoogle Scholar
  10. 10.
    G. Z. Kaziev, O. A. Kirichenko, A. I. Stash, O. S. Quiñones, E. A. Solovieva, and Yu. Chen. J. Struct. Chem., 2014, 54(4), 674–681.CrossRefGoogle Scholar
  11. 11.
    G. Z. Kaziev, A. F. Stepnova, P. V. Dorovatovskii, O. S. Quiñones, Ya. V. Zubavichus, V. N. Khrustalev, and L. K. Vasyanina. Zh. Obshch. Khim., 2016, 86(7), 1164–1169.Google Scholar
  12. 12.
    T. G. G. Battye, L. Kontogiannis, O. Johnson, H. R. Powell, and A. G. W. Leslie. Acta Crystallogr., 2011, D67, 271–281.Google Scholar
  13. 13.
    P. R. Evans. Acta Crystallogr., 2005, D62, 72–82.Google Scholar
  14. 14.
    G. M. Sheldrick. Acta Crystallogr., 2015, C71, 3–8.Google Scholar
  15. 15.
    V. S. Sergienko and M. A. Porai-Koshits. Crystal structural aspect of the structure of isopoly-and heteropolycompounds. / Itogi Nauki i Tekhniki. Ser. Kristallokhimiya. V. 19. VINITI, Moscow 1985,79.Google Scholar
  16. 16.
    J. F. Keggin. Proc. R. Soc. London, Ser. A., 2002, 144, 75–100.CrossRefGoogle Scholar
  17. 17.
    L. P. Kazanskii. Heteropolycomplexes. Molecular, protonic, and electronic structure [in Russian]. Doc. … diss., 1987.Google Scholar
  18. 18.
    F. A. Cotton and R. M. Wing. Inorg. Chem., 1965, 4, 865–873.Google Scholar
  19. 19.
    M. A. Pora`-Koshits and L. O. Atovmyan. Structure of isopoly- and heteropolycompounds / Itogi Nauki i Tekhniki. Ser. Kristallokhimiya. V. 19. VINITI, Moscow, 1985, 3–75.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. F. Stepnova
    • 1
  • G. Z. Kaziev
    • 1
  • P. V. Dorovatovskii
    • 2
  • Ya. V. Zubavichus
    • 2
  • Saúl Holguín Quiñones
    • 3
  • Nguen Van Bang
    • 1
  • V. N. Khrustalev
    • 4
  1. 1.Moscow Pedagogical State UniversityMoscowRussia
  2. 2.National Research Center “Kurchatov Institute”MoscowRussia
  3. 3.Universidad autónoma metropolitanaAzcapotzalcoMéxico
  4. 4.Russian University of Peoples FriendshipMoscowRussia

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