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Journal of Structural Chemistry

, Volume 56, Issue 8, pp 1545–1549 | Cite as

Nickel(II) complex containing 5,5′-dimethyl-2,2′-bipyridine: Crystal structure and luminescent properties

  • A. AbediEmail author
  • E. Saemian
  • V. Amani
Structure and Properties of Coordination Compounds

Abstract

[Ni(5,5′-dmbipy)2Cl2]·3H2O (1) complex was obtained from the reaction of NiCl2·6H2O with 5,5′-dimethyl-2,2′-bipyridine (5,5′-dmbipy) in a mixture of CH3OH/CH3CN. This complex was characterized by elemental analysis, IR, UV-Vis and luminescence spectroscopy, and its structure was determined by the single-crystal diffraction method. The Ni atom has a distorted octahedral coordination by four N atoms from two 5,5′-dmbipy ligands and two Cl anions.

Keywords

nickel(II) 5,5′-dimethyl-2,2′-bipyridine crystal structure luminescent properties 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  1. 1.Department of Chemistry, North Tehran BranchIslamic Azad UniversityTehranIran
  2. 2.Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) BranchIslamic Azad UniversityTehranIran

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