Advertisement

JETP Letters

, Volume 108, Issue 9, pp 627–632 | Cite as

Liquid–Gas Equilibrium in Nanoparticle Network-Forming Systems

  • R. E. RyltsevEmail author
  • L. D. Son
  • K. Yu. Shunyaev
Condensed Matter
  • 12 Downloads

Abstract

Mechanisms of phase formation in solutions of nano- and microparticles with anisotropic effective interactions have actively been discussed in the last years. Possible types of miscibility gaps for colloidal suspensions with anisotropic interaction have been analyzed within a statistical model including the variation of the reactivity of particles without a priori assumptions on the structure of clusters. It has been shown that the variation of model parameters allows the description of all observed miscibility gaps within a unified formalism. In particular, diagrams with the homogeneity region at zero temperature, closed loops, a lower critical point, and infinite immiscibility corridors have been obtained. Some types of diagrams have been described for the first time. It has been shown that a variable reactivity of particles is a key factor determining the type of phase diagram.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    E. Bianchi, R. Blaak, and C. N. Likos, Phys. Chem. Chem. Phys. 13, 6397 (2011).CrossRefGoogle Scholar
  2. 2.
    M. I. Shliomis, Phys. Usp. 17, 153 (1974).ADSCrossRefGoogle Scholar
  3. 3.
    P. N. Pusey and W. van Megen, Nature (London, U.K.) 320, 340 (1986).ADSCrossRefGoogle Scholar
  4. 4.
    T. Tlusty and S. A. Safran, Science (Washington, DC, U. S.) 290, 1328 (2000).ADSCrossRefGoogle Scholar
  5. 5.
    E. Bianchi, J. Largo, P. Tartaglia, E. Zacarellli, and F. Sciortino, Phys. Rev. Lett. 97, 168301 (2006).ADSCrossRefGoogle Scholar
  6. 6.
    B. Ruzicka, E. Zaccarelli, L. Zulian, R. Angelini, M. Sztucki, A. Moussaid, and F. Sciortino, Nat. Mater. 10, 56 (2011).ADSCrossRefGoogle Scholar
  7. 7.
    J. Russo, J. M. Tavares, P. I. C. Teixeira, M. M. Telo da Gama, and F. Sciortino, Phys. Rev. Lett. 106, 085703 (2011).ADSCrossRefGoogle Scholar
  8. 8.
    J. Russo, J. M. Tavares, P. I. C. Teixeira, M. M. Telo da Gama, and F. Sciortino, J. Chem. Phys. 135, 034501 (2011).ADSCrossRefGoogle Scholar
  9. 9.
    N. G. Almarza, Phys. Rev. E 86, 030101(R) (2012).Google Scholar
  10. 10.
    I. Erukhimovich and A. V. Ermoshkin, J. Chem. Phys. 116, 368 (2002).ADSCrossRefGoogle Scholar
  11. 11.
    M. V. Belousov, M. V. Tamm, and I. Y. Erukhimovich, J. Chem. Phys. 128, 114510 (2008).ADSCrossRefGoogle Scholar
  12. 12.
    R. E. Ryltcev and L. D. Son, Phys. A (Amsterdam, Neth.) 368, 101 (2006).ADSCrossRefGoogle Scholar
  13. 13.
    R. E. Ryl’tsev and L. D. Son, J. Exp. Theor. Phys. 110, 504 (2010).CrossRefGoogle Scholar
  14. 14.
    R. E. Ryltsev, L. D. Son, and K. Yu. Shunyaev, JETP Lett. 98, 573 (2013).ADSCrossRefGoogle Scholar
  15. 15.
    L. D. Son, R. E. Ryltcev, V. E. Sidorov, and D. Sordelet, Mater. Sci. Eng. A 449–451, 582 (2007).Google Scholar
  16. 16.
    L. D. Son, R. E. Ryltsev, and V. E. Sidorov, J. Non-Cryst. Solids 353, 3722 (2007).ADSCrossRefGoogle Scholar
  17. 17.
    R. E. Ryltsev and L. D. Son, Phys. B (Amsterdam, Neth.) 406, 3625 (2011).ADSCrossRefGoogle Scholar
  18. 18.
    T. V. Kulikova, A. V. Majorova, K. Yu. Shunyaev, and R. E. Ryltsev, Phys. B (Amsterdam, Neth.) 466, 90 (2015).ADSCrossRefGoogle Scholar
  19. 19.
    S. I. Kuchanov, S. V. Korolev, and S. V. Panyukov, in Applications of Graph Theory to Chemistry (Nauka, Novosibirsk, 8) [in Russian].Google Scholar
  20. 20.
    P. J. Flory, J. Phys. Chem. 46, 132 (1942).CrossRefGoogle Scholar
  21. 21.
    W. H. Stockmayer, J. Chem. Phys. 11, 45 (1943).ADSCrossRefGoogle Scholar
  22. 22.
    F. Tanaka and W. H. Stockmayer, Macromolecules 27, 3943 (1994).ADSCrossRefGoogle Scholar
  23. 23.
    A. N. Semenov and M. Rubinstein, Macromolecules 31, 1373 (1998).ADSCrossRefGoogle Scholar
  24. 24.
    A. Coniglio, H. E. Stanley, and W. Klein, Phys. Rev. Lett. 42, 518 (1979).ADSCrossRefGoogle Scholar
  25. 25.
    A. Coniglio, H. E. Stanley, and W. Klein, Phys. Rev. B 25, 6805 (1982).ADSMathSciNetCrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • R. E. Ryltsev
    • 1
    • 2
    Email author
  • L. D. Son
    • 2
    • 3
  • K. Yu. Shunyaev
    • 1
    • 2
  1. 1.Institute of Metallurgy, Ural BranchRussian Academy of SciencesYekaterinburgRussia
  2. 2.Ural Federal UniversityYekaterinburgRussia
  3. 3.Ural State Pedagogical UniversityYekaterinburgRussia

Personalised recommendations