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Inorganic Materials

, Volume 55, Issue 11, pp 1151–1155 | Cite as

Mullite Synthesis from High-Temperature Solution

  • V. A. Maslov
  • V. V. Voronov
  • L. D. Iskhakova
  • E. G. Yarotskaya
  • P. P. FedorovEmail author
Article
  • 10 Downloads

Abstract—We have studied mullite formation during recrystallization of alumina-rich ceramics from a high-temperature solution. The use of alkali metal-containing fluxes leads to crystallization of the corresponding aluminosilicates. A positive result has been obtained using a PbO–V2O5 melt as a solvent, with incongruent mullite dissolution in it.

Keywords:

mullite fluxes crystallization aluminosilicates silica lead vanadate 

Notes

ACKNOWLEDGMENTS

In this study, we used equipment at the Shared Research Facilities Centers at the Prokhorov General Physics Institute of the Russian Academy of Sciences, and at the Fiber Optics Research Center, Russian Academy of Sciences.

REFERENCES

  1. 1.
    Grosheva, V.M., Karpinos, D.M., and Panasevich, I.M., Sinteticheskii mullit i materialy na ego osnove (Synthetic Mullite and Mullite-Based Materials), Kiev: Tekhnika, 1971.Google Scholar
  2. 2.
    Aksay, I.A., Dabbs, D.M., and Sarikaya, M., Mullite for structural, electronic, and optical applications, J. Am. Ceram. Soc., 1991, vol. 74, pp. 2345–2357.Google Scholar
  3. 3.
    Yarotskaya, E.G., Polyanskii, E.V., Yarotskii, V.G., and Golenko, V.P., Mullite, in Sintez Mineralov (Synthesis of Minerals) Aleksandrov: VNIISIMS, 2000, vol. 2, pp. 142–178.Google Scholar
  4. 4.
    Scneider, H. and Komarneri, S., Mullite. Weinheim: WILEY-VCH, 2005.CrossRefGoogle Scholar
  5. 5.
    Scneider, H., Fischer, R.X., and Screuer, J., Mullite: crystal structure and related properties, J. Am. Ceram. Soc., 2015, vol. 98, pp. 2948–2967.CrossRefGoogle Scholar
  6. 6.
    Yarotskaya, E.G. and Fedorov, P.P., Mullite and its isomorphous substitutions, Condensed Matter and Interphases, 2018, vol. 20, no. 4, pp. 537–544.Google Scholar
  7. 7.
    Dong, X., Liu, J., Li, X., et al., Electrospun mullite nanofibres from diphasic mullite sol, J. Am. Ceram. Soc., 2018, vol. 101, pp. 3425–3433.Google Scholar
  8. 8.
    Lambotte, G. and Chartrand, P., Thermodynamic evaluation and optimization of the Al2O3–SiO2–AlF3–SiF4 reciprocal system using the modified quasichemical model, J. Am. Ceram. Soc., 2011, vol. 94, pp. 4000–4008.CrossRefGoogle Scholar
  9. 9.
    Igami, Y., Ohi, S., and Miyake, A., Sillimanite–mullite transformation observed in synchrotron X-ray diffraction experiments, J. Am. Ceram. Soc., 2017, vol. 100, pp. 4928–4937.CrossRefGoogle Scholar
  10. 10.
    Fedorov, P.P., Transformations of Tx phase diagrams of binary systems in the condensed state: II. Phase equilibria under constraints, Russ. J. Phys. Chem. A, 1999, vol. 73, no. 9, pp. 1387–1392.Google Scholar
  11. 11.
    Kriven, W.N., Solid solution range and microstructures of melt-grown mullite, J. Am. Ceram. Soc., 1983, vol. 66, no. 9, pp. 649–654.CrossRefGoogle Scholar
  12. 12.
    Wilke, K.-Th., Methoden der Kristallzüchtung, Berlin: Wissenschaften, 1963.Google Scholar
  13. 13.
    Kuz’minov, Yu.S., Lomonova, E.E., and Osiko, V.V., Tugoplavkie materialy iz kholodnogo tiglya (Refractory Materials from a Cold Crucible), Moscow: Nauka, 2004.Google Scholar
  14. 14.
    Timofeeva, V.A., Rost kristallov iz rastvor-rasplavov (Crystal Growth from High-Temperature Solutions), Moscow: Nauka, 1978.Google Scholar
  15. 15.
    Maslov, V.A., Emerald crystal growth from fluxes by Czochralsky technique, 11th Int. Conf. on Crystal Growth (ICCG-11), Hague, 1995, abstract no. O303.06.Google Scholar
  16. 16.
    Eitel, W., The Physical Chemistry of Silicates, Chicago: Univ. of Chicago, 1954.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. A. Maslov
    • 1
  • V. V. Voronov
    • 1
  • L. D. Iskhakova
    • 2
  • E. G. Yarotskaya
    • 1
  • P. P. Fedorov
    • 1
    Email author
  1. 1.Prokhorov General Physics Institute of the Russian Academy of SciencesMoscowRussia
  2. 2.Fiber Optics Research Center, Russian Academy of SciencesMoscowRussia

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