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Inorganic Materials

, Volume 55, Issue 10, pp 1007–1013 | Cite as

Structural and Magnetic Properties of a BaFe12– xScxO19 Substituted Hexagonal Ferrite

  • V. V. Korovushkin
  • M. N. Shipko
  • V. G. Kostishin
  • I. M. Isaev
  • A. Yu. Mironovich
  • S. V. TrukhanovEmail author
  • A. V. Trukhanov
Article
  • 21 Downloads

Abstract—We have studied the effect of Sc3+ substitution for Fe3+ ions on the magnetic properties and crystal structure of BaFe12– xScxO19 hexaferrites. Based on Mössbauer spectroscopy data, we have assessed the distribution of scandium ions over sublattices and their effect on magnetic characteristics of the materials. The specific magnetization and coercive force of the ferrites have been shown to depend on the location and concentration of scandium ions in the crystal structure. The hexaferrite with x > 0.6 has been found to have a noncollinear magnetic structure.

Keywords:

hexaferrites diamagnetic substitution Mössbauer spectroscopy magnetic structure 

Notes

REFERENCES

  1. 1.
    Ketsko, V.A., Beresnev, E.N., Kop’eva, M.A., Rjabkova, L.V., Baranchikov, A.E., Stognij, A.I., Trukhanov, A.V., and Kuznetsov, N.T., Specifics of the pyrohydrolytic and solid-phase syntheses of solid solutions in the (MgGa2O4)x(MgFe2O4)1 – x system, Russ. J. Inorg. Chem., 2010, vol. 55, no. 3, pp. 427–429.CrossRefGoogle Scholar
  2. 2.
    Nipan, G.D., Ketsko, V.A., Stognij, A.I., Trukhanov, A.V., Kol’tsova, T.N., Kop’eva, M.A., Elesina, L.V., and Kuznetsov, N.T., Properties of Mg(Fe1 – xGax)2O4 + δ solid solutions in stable and metastable states, Inorg. Mater., 2010, vol. 46, no. 4, pp. 429–433.CrossRefGoogle Scholar
  3. 3.
    Stognij, A.I., Trukhanov, A.V., Ketsko, V.A., and Nipan, G.D., Properties of Mg(Fe0.8Ga0.2)2O4 + δ ceramics and films, Inorg. Mater., 2011, vol. 47, no. 2, pp. 204–208.CrossRefGoogle Scholar
  4. 4.
    Trukhanov, A.V., Stognij, A.I., Novitskii, N.N., Trukhanov, S.V., Ketsko, V.A., and Nipan, G.D., Growth and structure of Mg(Fe0.8 + xGa0.2 + y)2O4 – δ films, Inorg. Mater., 2011, vol. 47, no. 9, pp. 1025–1028.CrossRefGoogle Scholar
  5. 5.
    Trukhanov, A.V., Stognij, A.I., Trukhanov, S.V., Geraskin, A.A., and Ketsko, V.A., Crystal structure and magnetic properties of nanosized Mg(Fe0.8Ga0.2)2O4 − δ films on Si substrates, Crystallogr. Rep., 2013, vol. 58, no. 3, pp. 498–504.CrossRefGoogle Scholar
  6. 6.
    Trukhanov, S.V., Trukhanov, A.V., Panina, L.V., Kazakevich, I.S., Turchenko, V.A., Oleinik, V.V., Yakovenko, E.C., and Matsui, L.Yu., Magnetic and absorbing properties of M-type substituted hexaferrites BaFe12 − xGaxO19 (0.1< x <1.2), J. Exp. Theor. Phys., 2016, vol. 123, no. 3, pp. 461–469.CrossRefGoogle Scholar
  7. 7.
    Smirnova, M.N., Geras’kin, A.A., Stognii, A.I., Golikova, O.L., Bespalov, A.V., Trukhanov, A.V., Kop’eva, M.A., Beresnev, E.N., and Ketsko, V.A., Crystallization of Mg(Fe0.8Ga0.2)2O4 – δ films on silicon with SiO2 and TiO2 buffer layers, Russ. J. Inorg. Chem., 2014, vol. 59, no. 7, pp. 778–782.CrossRefGoogle Scholar
  8. 8.
    Trukhanov, A.V., Trukhanov, S.V., Kostishin, V.G., Panina, L.V., Salem, M.M., Kazakevich, I.S., Turchenko, V.A., Kochervinskii, V.V., and Krivchenya, D.A., Multiferroic properties and structural features of M‑type Al-substituted barium hexaferrites, Phys. Solid State, 2017, vol. 59, no. 4, pp. 737–745.CrossRefGoogle Scholar
  9. 9.
    Trukhanov, A.V., Turchenko, V.A., Bobrikov, I.A., Trukhanov, S.V., and Balagurov, A.M., Investigation of the crystal and magnetic structures of BaFe12–xAlxO19 solid solutions (x = 0.1–1.2), Crystallogr. Rep., 2015, vol. 60, no. 5, pp. 629–635.CrossRefGoogle Scholar
  10. 10.
    Trukhanov, S.V., Trukhanov, A.V., Turchenko, V.A., Kostishin, V.G., Panina, L.V., Kazakevich, I.S., and Balagurov, A.M., Crystal structure and magnetic properties of the BaFe12 – xInxO19 (x = 0.1–1.2) solid solutions, J. Magn. Magn. Mater., 2016, vol. 417, pp. 130–136.CrossRefGoogle Scholar
  11. 11.
    Kojima, H., Fundamental properties of hexagonal ferrites with magnetoplumbite structure, Ferromagn. Mater., 1982, vol. 3, pp. 305–440.Google Scholar
  12. 12.
    Shipko, M.N., Rozin, E.G., Bondar’, V.I., and Bashkirov, L.A., Mössbauer study of the cation distribution in the phase composition of hexagonal barium calcium ferrites, Izv. Akad. Nauk BSSR, Ser. Fiz.-Mat. Nauk, 1984, vol. 1, pp. 70–73.Google Scholar
  13. 13.
    Smit, J. and Wijn, H.P.J., Ferrites: Physical Properties of Ferromagnetic Oxides in Relation to Their Technical Applications, Eindhoven: Philips Tech. Libr., 1959.Google Scholar
  14. 14.
    Kamzin, A.S., Ol’khovik, L.P., and Rozenbaum, V.L., Mössbauer study of the surface and bulk magnetic structures of scandium-substituted M-type hexaferrites, Fiz. Tverd. Tela (S.-Peterburg), 1999, vol. 41, no. 3, pp. 483–490.Google Scholar
  15. 15.
    Kostishin, V.G., Andreev, V.G., Chitanov, D.N., Nalogin, A.G., Ursulyak, N.D., Alekseev, A.A., Timofeev, A.V., and Adamtsov, A.Yu., Effects of base composition and dopants on the properties of hexagonal ferrites, Russ. J. Inorg. Chem., 2016, vol. 61, no. 3, pp. 279–284.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. V. Korovushkin
    • 1
  • M. N. Shipko
    • 2
  • V. G. Kostishin
    • 1
  • I. M. Isaev
    • 1
  • A. Yu. Mironovich
    • 1
  • S. V. Trukhanov
    • 3
    Email author
  • A. V. Trukhanov
    • 1
    • 3
  1. 1.Moscow Institute of Steel and Alloys (National University of Science and Technology)MoscowRussia
  2. 2.Lenin State Power UniversityIvanovoRussia
  3. 3.Scientific–Practical Materials Research Centre, Belarussian Academy of SciencesMinskBelarus

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