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High Temperature

, Volume 56, Issue 5, pp 689–693 | Cite as

Speed of Sound and Adiabatic Compressibility of Binary Sodium Halide Mixtures

  • P. V. Stepanov
THERMOPHYSICAL PROPERTIES OF MATERIALS
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Abstract

We used the impulse-temporal method to measure the speed of sound in NaCl–NaBr, NaCl–NaI, and NaBr–NaI binary molten mixtures with respect to temperature and composition. Using the literature data on density, we calculated the adiabatic compressibility of these systems. We obtained the negative deviations of the speed of sound and the positive deviations for the compressibility from the additive values; the deviation values depend on the size ratio of the mixed anions.

Notes

REFERENCES

  1. 1.
    Nozdrev, V.F., Primenenie ul’traakustiki v molekulyarnoi fizike (Application of Ultra-Acoustics in Molecular Physics), Moscow: Gos. Izd. Fiz. Mat. Lit., 1958.Google Scholar
  2. 2.
    Neruchev, Yu.A., Bolotnikov, M.F., and Zotov, V.V., High Temp., 2005, vol. 43, no. 2, p. 266.CrossRefGoogle Scholar
  3. 3.
    Molten Salts Chemistry: From Lab to Applications, Lantelme, F. and Groult, H., Eds., Amsterdam: Elsevier, 2013.Google Scholar
  4. 4.
    Cairns, E.I. and Stennenberg, R.K., High-temperature batteries, in Prog. High-Temp. Phys. Chem., Oxford: Argonne Natl. Lab., Chem. Eng. Div., 1973, vol. 5, p. 63.Google Scholar
  5. 5.
    Ignat’ev, V.V., Feinberg, O.S., Zagnit’ko, A.V., Merzlyakov, A.V., Surenkov, A.I., Panov, A.V., Subbotin, V.G., Afonichkin, V.K., Khokhlov, V.A., and Kormilitsyn, M.V., At. Energ., 2012, vol. 112, no. 3, p. 135.Google Scholar
  6. 6.
    Holm, J.L., Acta Chem. Scand., 1971, vol. 25, no. 10, p. 3609.CrossRefGoogle Scholar
  7. 7.
    Smirnov, M.V. and Stepanov, V.P., Electrochim. Acta, 1982, vol. 27, no. 11, p. 1551.CrossRefGoogle Scholar
  8. 8.
    Sternberg, S. and Vasilescu, V., Rev. Roum. Chim., 1970, vol. 15, no. 11, p. 1665.Google Scholar
  9. 9.
    Smirnov, M.V. and Bukharov, A.N., Electrochim. Acta, 1988, vol. 33, no. 2, p. 213.CrossRefGoogle Scholar
  10. 10.
    Khokhlov, V.A., Smirnov, M.V., and Filatov, E.S., Teplofiz. Vys. Temp., 1983, vol. 21, no. 2, p. 260.Google Scholar
  11. 11.
    Smirnov, M.V., Stepanov, V.P., and Khokhlov, V.A., Rasplavy, 1987, vol. 1, no. 1, p. 64.Google Scholar
  12. 12.
    Rukavishnikova, I.V., Lokett, V.N., Burukhin, A.S., and Stepanov, V.P., Russ. J. Phys. Chem. A, 2006, vol. 80, no. 12, p. 1902.CrossRefGoogle Scholar
  13. 13.
    Stepanov, V.P. and Minchenko, V.I., J. Chem. Thermodyn., 2011, vol. 43, no. 3, p. 467.CrossRefGoogle Scholar
  14. 14.
    Lockett, V.N., Rukavishnikova, I.V., Stepanov, V.P., and Tkachev, N.K., Phys. Chem. Chem. Phys., 2010, vol. 12, no. 5, p. 1139.CrossRefGoogle Scholar
  15. 15.
    Stepanov, V.P., Babushkina, L.M., and Dokashenko, S.I., J. Chem. Thermodyn., 2012, vol. 51, no. 8, p. 12.CrossRefGoogle Scholar
  16. 16.
    Stepanov, V.P. and Minchenko, V.I., J. Chem. Thermodyn., 2013, vol. 59, no. 4, p. 250.CrossRefGoogle Scholar
  17. 17.
    Stepanov, V.P. and Minchenko, V.I., J. Chem. Thermodyn., 2015, vol. 87, no. 8, p. 65.CrossRefGoogle Scholar
  18. 18.
    Brookes, H.C. and Paul, R.L., Z. Naturforsch., A: Phys. Sci., 1975, vol. 30a, no. 1, p. 64.Google Scholar
  19. 19.
    Minchenko, V.I., Smirnov, M.V., and Stepanov, V.P., Zh. Fiz. Khim., 1981, vol. 55, no. 5, p. 1151.Google Scholar
  20. 20.
    Zuca, S. and Jonesku-Vasu, L., Rev. Roum. Chim., 1967, vol. 12, no. 11, p. 1285.Google Scholar
  21. 21.
    Zuca, S. and Olteanu, M., Rev. Roum. Chim., 1968, vol. 13, no. 12, p. 1567.Google Scholar
  22. 22.
    Sternberg, S. and Vasilevscu, V., Rev. Roum. Chim., 1967, vol. 12, no. 10, p. 1107.Google Scholar
  23. 23.
    Prissyajnyi, V., Vasilescu, V., and Sternberg, S., J. Chem. Thermodyn., 1971, vol. 3, no. 6, p. 867.CrossRefGoogle Scholar
  24. 24.
    Warren, R.W., Rev. Sci. Instrum., 1965, vol. 36, no. 6, p. 731.ADSCrossRefGoogle Scholar
  25. 25.
    Shishkin, V.Yu. and Mityaev, V.S., Izv. Akad. Nauk SSSR, Neorg. Mater., 1982, vol. 18, no. 11, p. 1917.Google Scholar
  26. 26.
    Bockris, J.O. and Richards, N., Proc. R. Soc. A, 1957, vol. 241, p. 44.ADSCrossRefGoogle Scholar
  27. 27.
    Sternberg, S. and Vasilescu, V., J. Chem. Thermodyn., 1971, vol. 3, no. 6, p. 877.CrossRefGoogle Scholar
  28. 28.
    Levy, H.A., Agron, P.A., Bredig, M.A., and Danford, M.D., Ann. N.Y. Acad. Sci., 1960, vol. 79, no. 11, p. 762.ADSCrossRefGoogle Scholar
  29. 29.
    Antonov, B.D., Zh. Strukt. Khim., 1975, vol. 16, p. 501.Google Scholar
  30. 30.
    Wilson, M., Madden, P.A., and Costa-Cabral, B.J., J. Phys. Chem., 1996, vol. 100, no. 4, p. 1227.CrossRefGoogle Scholar
  31. 31.
    Tkachev, N.K., High Temp., 1998, vol. 36, no. 4, p. 559.Google Scholar
  32. 32.
    Tkachev, N.K. and Zinatulina, A.R., Russ. J. Phys. Chem. A, 2013, vol. 87, no. 9, p. 1457.CrossRefGoogle Scholar
  33. 33.
    Tkachev, N.K. and Peshkina, K.G., High Temp., 2016, vol. 54, no. 2, p. 300.CrossRefGoogle Scholar
  34. 34.
    Minchenko, V.I., Smirnov, M.V., and Konovalov, Yu.V., Rasplavy, 1988, vol. 2, no. 4, p. 110.Google Scholar
  35. 35.
    Bukhalova, G.A., Shegurova, G.A., and Yagub’yan, E.S., in Tr. V Vses. soveshch. po fiz. khimii i elektrokhimii rasplavlennykh solei, oksidnykh rasplavov i tverdykh elektrolitov (Proc. V All-Union Meeting on Physical Chemistry and Electrochemistry of Molten Salts, Oxide Melts, and Solid Electrolytes), Sverdlovsk: Uralsk. Fil. Akad. Nauk SSSR, 1973, vol. 1, p. 4.Google Scholar
  36. 36.
    Rao, M.R., J. Chem. Phys., 1941, vol. 9, p. 682.ADSCrossRefGoogle Scholar
  37. 37.
    Kudryavtsev, B.B., Primenenie ul’traakusticheskikh metodov v praktike fiziko-khimicheskikh issledovanii (Application of Ultra-Acoustic Methods in the Practice of Physical and Chemical Research), Moscow: Gos. Izd. Teor. Tekh. Lit., 1952.Google Scholar
  38. 38.
    Higgs, R.V. and Litovitz, T.A., J. Am. Acoust. Soc., 1960, vol. 32, no. 9, p. 1103.CrossRefGoogle Scholar

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© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  1. 1.Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of SciencesYekaterinburgRussia
  2. 2.Ural State UniversityYekaterinburgRussia

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