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High Energy Chemistry

, Volume 52, Issue 5, pp 446–448 | Cite as

The Quantum Yield of Singlet Oxygen in Thermal Degradation of Alcohol Hydrotrioxides

  • L. R. Khalitova
  • A. V. Antipin
  • S. A. Grabovskii
  • N. N. Kabal’nova
Chemiluminescence
  • 2 Downloads

Abstract

The yield of singlet oxygen (1О2) in the decomposition of a number of hydrotrioxides of alcohols (cyclobutanol, cyclopentanol, cyclohexanol, cycloheptanol, cyclooctanol, L-menthol, 1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, 1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol, heptan-4-ol, propanol-2, and 1-cyclopropylethanol) has been determined using the IR chemiluminescence technique. It has been shown that cyclopentanol, 1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol and 1-cyclopropylethanol hydrotrioxides are efficient sources of singlet oxygen; the yield of 1О2 reaches up to 58%.

Keywords

singlet oxygen hydrotrioxides chemiluminescence 

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References

  1. 1.
    Hatz, S., Lambert, J.-D.C., and Ogilby, P.R., Photochem. Photobiol. Sci., 2007, vol. 6, p. 1106.CrossRefGoogle Scholar
  2. 2.
    Bregnhoj, M., Westberg, M., Minaev, B.F., and Ogilby, P.R., Acc. Chem. Res., 2017, vol. 50, p. 1920.CrossRefGoogle Scholar
  3. 3.
    Shereshovets, V.V., Khursan, S.L., Komissarov, V.D., and Tolstikov, G.A., Usp. Khim., 2001, vol. 70, no. 2, p.123.CrossRefGoogle Scholar
  4. 4.
    Abdrakhmanova, A.R., Khalitova, L.R., Spirikhin, L.V., Dokichev, V.A., Grabovskii, S.A., and Kabal’nova, N.N., Izv. Akad. Nauk, Ser. Khim., 2007, no. 2, p.263.Google Scholar
  5. 5.
    Grabovskii, S.A., Khalitova, L.R., Fedorova, A.V., Lobov, A.N., Rol’nik, L.Z., and Kabal’nova, N.N., Izv. Akad. Nauk, Ser. Khim., 2016, no. 2, p.464.Google Scholar
  6. 6.
    Shereshovets, V.V., Shafikov, N.Ya., Galieva, F.A., Sadykov, R.A., Panasenko, R.A., and Komissarov, V.D., Izv. Akad. Nauk SSSR, Ser. Khim., 1982, no. 5, p. 1177.Google Scholar
  7. 7.
    Caminade, A.M., Khatib, F.E., Koenig, M., and Aubry, J.M., Can. J. Chem., 1985, vol. 63, p. 3203.CrossRefGoogle Scholar
  8. 8.
    Khursan, S.L., Khalizov, A.F., Avzyanova, E.V., Yakupov, M.Z., and Shereshovets, V.V., Zh. Fiz. Khim., 2001, vol. 75, no. 7, p. 1225.Google Scholar
  9. 9.
    Niu, Q.J. and Mendenhall, G.D., J. Am. Chem. Soc., 1992, vol. 114, p.165.CrossRefGoogle Scholar
  10. 10.
    CRC Handbook of Chemistry and Physics, Lide, D.R., Ed., Boca Raton, FL: CRC, 2002, 83rd ed.Google Scholar
  11. 11.
    Levy, G.C. and Nelson, G.L., Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, New York: Wiley–Interscience, 1972.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. R. Khalitova
    • 1
  • A. V. Antipin
    • 1
  • S. A. Grabovskii
    • 1
  • N. N. Kabal’nova
    • 1
  1. 1.Ufa Institute of Chemistry, Ufa Federal Research CenterRussian Academy of SciencesUfaRussia

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