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Doklady Chemistry

, Volume 486, Issue 1, pp 126–129 | Cite as

Cyclotribromoveratrylene in Synthesis of Porphyrin-Containing Polyphenols

  • A. Ya. VainerEmail author
  • K. M. Dyumaev
  • A. M. Kovalenko
  • N. V. Barannik
  • R. M. Dragunskaya
  • S. V. Kotov
  • Ya. M. Pribysh
CHEMISTRY

Abstract

Porphyrin-containing polyphenols bonded to a cycloveratrylene macrocycle as a molecular platform have been synthesized. Polyphenols were obtained by the Suzuki–Miyaura reaction between cyclotribromoveratrylene and a boryl derivative of N,N'-diporphyrinaniline and subsequent chemical transformations. In particular, demethylation of the reaction product containing peripheral methoxy groups and subsequent blocking of the phenol hydroxyls by two different acid-labile protecting groups—cyclobutyldicyclopropylmethyl and 1-perfluoroethylcyclohexyl—led to a target polyphenol, which was then used for the development of a new positive photoresist capable of forming patterns with a 16 nm resolution when exposed to radiation at a wavelength of 13.5 nm.

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. Ya. Vainer
    • 1
    Email author
  • K. M. Dyumaev
    • 1
  • A. M. Kovalenko
    • 1
  • N. V. Barannik
    • 1
  • R. M. Dragunskaya
    • 1
  • S. V. Kotov
    • 1
  • Ya. M. Pribysh
    • 1
  1. 1.All-Russian Research Institute of Medicinal and Aromatic PlantsMoscowRussia

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