Abstract
A convenient preparative route has been developed for the synthesis of 2-azido-4-R-6-R'-sym-triazines, which are promising synthons in organic synthesis. A series of 2-(1-triazolyl)-sym-triazine derivatives has been synthesized for the first time from the obtained azides and acetylacetone or acetoacetic ester.
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REFERENCES
S. N. Mikhailychenko, A. A. Chesniuk, V. E. Zavodnik, S. I. Firgang, L. D. Koniushkin, and V. N. Zaplishny, Khim. Geterotsikl. Soedin., 326 (2002).
D. H. R. Barton and W. D. Ollis (editors), Comprehensive Organic Chemistry, Vol. 3, Pergamon, Oxford (1979).
Weygand-Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya, Moscow (1962).
A. A. Chesniuk, S. N. Mikhailychenko, V. S. Zavodnov, and V. N. Zaplishny, Khim. Geterotsikl. Soedin., 197 (2002).
A. Gorup, M. Kvacic, B. Kranjc-Skraba, B. Mihelcic, S. Simonic, B. Stanovnic, and M. Tisler, Tetrahedron, 30, 2251 (1974).
L. V. Batog, V. Yu. Rozhkov, Yu. V. Khronov, N. V. Pyatakova, O. G. Busygina, I. S. Severina, and N. N. Makhova, Russian Patent 2158265; Byull. Izobret., No. 30, 187 (2000).
E. B. Nikolaenkova, V. P. Krivopalov, and O. P. Shkurko, in: Nitrogen Heterocycles and Alkaloids [in Russian], Vol. 2, Iridium Press, Moscow (2001), p. 300.
G. M. Pogosyan, V. A. Pankratov, V. N. Zaplishny, and S. G. Matsoyan, in: Polytriazines [in Russian], Izd. Akad. Nauk ArmSSR, Erevan (1987), p. 615.
A. J. Gordon and R. A. Ford, Chemist's Companion, Handbook of Practical Data, Techniques and References, Wiley-Interscience, New York (1972), 560 pp.
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Mikhailychenko, S.N., Chesniuk, A.A., Koniushkin, L.D. et al. Derivatives of sym-Triazine. 3. Synthesis and Some Conversions of Monoazides of the Triazine Series. Chemistry of Heterocyclic Compounds 40, 1162–1168 (2004). https://doi.org/10.1023/B:COHC.0000048289.56361.4b
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DOI: https://doi.org/10.1023/B:COHC.0000048289.56361.4b