Abstract
It has been shown that, depending on the structure, the products of dehydrochlorination of N-benzyltrifluoroacetimidoyl chlorides react with C60 under the action of triethylamine as a [3 + 2] cycloaddition (with the formation of fulleropyrrolines) or a [4 + 2] cycloaddition (with the formation of fulleropiperideines).
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Reinov, M.V., Yurovskaya, M.A., Streletskiy, A.V. et al. Heterocyclic Derivatives of Fullerene C60. 2. Cycloaddition to Fullerene C60 of the Products of Dehydrochlorination of N-Benzyltrifluoroacetimidoyl Chlorides. Chemistry of Heterocyclic Compounds 40, 1150–1154 (2004). https://doi.org/10.1023/B:COHC.0000048287.59108.e2
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DOI: https://doi.org/10.1023/B:COHC.0000048287.59108.e2