Skip to main content
SpringerLink
Log in

Characteristics of the Dissociative Ionization of 9-Aryl(hetaryl)-3,3,6,6-tetramethyldecahydroacridine-1,8-diones under the Influence of Electron Impact

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The mass spectra of 9-aryl(hetaryl)-3,3,6,6-tetramethyldecahydroacridine-1,8-diones have been studied and the basic directions of their dissociative ionization under the influence of electron impact have been elucidated. It has been shown that the decomposition pathways of decahydroacridine-1,8-diones depend on the nature of the substituents at position 10 and is connected with the preferential formation of a pyridinium structure with subsequent retrodiene decomposition of the molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. P. Shanmugasundaram, K. J. Prabahar, and V. T. Ramakrishnan, J. Heterocycl. Chem., 30, 1003 (1993).

    Google Scholar 

  2. A. A. Bakibaev and V. D. Filimonov, Zh. Org. Khim., 25, 1579 (1989).

    Google Scholar 

  3. T. G. Nikolaeva, Yu. M. Shchekotikhin, A. S. Ponomarev, and A. P. Kriven'ko, Khim. Geterotsikl. Soed., 475 (2000).

  4. Yu. M. Shchekotikhin, T. G. Nikolaeva, G. M. Shub, and A. P. Kriven'ko, Khim.-farm. Zhur., No. 4, 29 (2001).

  5. Yu. M. Shchekotikhin, Yu. A. Getmanenko, T. G. Nikolaeva, and A. P. Kriven'ko, Khim. Geterotsikl. Soed., 1344 (2001).

  6. T. G. Nikolaeva, Yu. M. Shchekotikhin, Yu. A. Getmanenko, and A. P. Kriven'ko, Khim. Geterotsikl. Soed., 416 (2000).

  7. T. G. Nikolaeva, and Yu. M. Shchekotikhin, Khim. Geterotsikl. Soed., 693 (2004).

  8. J. Baldas and Q. N. Porter, Tetrahedron Lett., 1351 (1968).

  9. C. Dagher, R. Hanna, P. B. Terentiev, Y. G. Boundel, A. N. Kost, and B. I. Maksimov, J. Heterocycl. Chem., 19, 645 (1982).

    Google Scholar 

  10. P. Gupka, J. Bella, and A. Martvon, Coll. Czech. Chem. Commun., 52, 742 (1987).

    Google Scholar 

  11. U. Eisner and J. Kuthan, Chem. Rev., 72, 1 (1972).

    Google Scholar 

  12. C. S. Barnes and J. H. Occolowitz, Austral. J. Chem., 16, 219 (1963).

    Google Scholar 

  13. R. A. Khmel'nitskii, Yu. A. Efremov, and N. V. Fedyainov, Izv TSKhA, No. 3, 199 (1978).

  14. J. Kuthan and A. Kurfurst, Ind. Eng. Chem, Prod. Res. Dev., 21, 191 (1982).

    Google Scholar 

  15. A. Maquestiau and P. Lejeune, Bull. Soc. Chim. Belg., 76, 133 (1967).

    Google Scholar 

  16. F. W. McLafferty, Mass Spectrometry of Organic Ions. Academic Press, New York (1963), p. 10.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. “Nita-Farm”, Saratov, 410005, Russia

    Yu. M. Shchekotikhin

  2. Saratov State University, Saratov, 410026, Russia

    T. G. Nickolaeva

Authors
  1. Yu. M. Shchekotikhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. G. Nickolaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shchekotikhin, Y.M., Nickolaeva, T.G. Characteristics of the Dissociative Ionization of 9-Aryl(hetaryl)-3,3,6,6-tetramethyldecahydroacridine-1,8-diones under the Influence of Electron Impact. Chemistry of Heterocyclic Compounds 40, 1031–1035 (2004). https://doi.org/10.1023/B:COHC.0000046693.85136.ac

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:COHC.0000046693.85136.ac

Search

Navigation