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Synthesis and Rotamerism of 9,10-Diarylsubstituted 1,2,3,4,5,6,7,8,9,10-Decahydroacridine-1,8-Diones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Condensation of aromatic aldehydes with 5,5-dimethylcylohexane-1,3-dione and primary arylamines gave 9,10-diaryl-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-diones. Several stereochemical features of the synthesized compounds are discussed. Dynamic NMR was used to determine the inversion barriers for the rotamers formed.

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Authors and Affiliations

  1. NTK Institute for Single Crystals, Kharkov, 61001, Ukraine

    V. A. Chebanov, V. E. Saraev, K. M. Kobzar', S. M. Desenko & E. A. Gura

  2. Kharkov National University, Kharkov, 61077, Ukraine

    V. D. Orlov

Authors
  1. V. A. Chebanov
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  2. V. E. Saraev
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  3. K. M. Kobzar'
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  4. S. M. Desenko
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  5. V. D. Orlov
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  6. E. A. Gura
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Chebanov, V.A., Saraev, V.E., Kobzar', K.M. et al. Synthesis and Rotamerism of 9,10-Diarylsubstituted 1,2,3,4,5,6,7,8,9,10-Decahydroacridine-1,8-Diones. Chemistry of Heterocyclic Compounds 40, 475–480 (2004). https://doi.org/10.1023/B:COHC.0000033541.49115.a0

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  • DOI: https://doi.org/10.1023/B:COHC.0000033541.49115.a0

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