Advertisement

Chemistry of Heterocyclic Compounds

, Volume 40, Issue 2, pp 166–176 | Cite as

Synthesis and Some Chemical Conversions of 2-([2,2]-5-Paracyclophanyl)pyrrole

  • A. V. Varlamov
  • T. N. Borisova
  • Boniface Nsabimana
  • A. I. Chernyshev
  • G. G. Aleksandrov
  • L. G. Voskressensky
Article

Abstract

2-([2,2]-5-Paracyclophanyl)pyrrole has been synthesized and nitration and formylation of it have been effected. The 1-β-cyanoethyl derivative and 2-formyl-5-paracyclophanyl-3H-pyrrolizine have been obtained from 5-formyl-2-([2,2]-5-paracyclophanyl)pyrrole by the action of acrylonitrile and acrolein respectively under Michael reaction conditions.

paracyclophane pyrrole heterocyclization addition Trofimov reaction 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    B. A. Trofimov and A. I. Mikhaleva, N-Vinylpyrroles [in Russian], Nauka, Novosibirsk (1984).Google Scholar
  2. 2.
    B. A. Trofimov, in R. A. Jones (editor), The Chemistry of Heterocyclic Compounds, Vol. 48, Pt II, Wiley, New York (1992), p. 131.Google Scholar
  3. 3.
    B. A. Trofimov and A. I. Mikhaleva, Zh. Org. Khim., 32, 1127 (1996).Google Scholar
  4. 4.
    T. N. Borisova, A. V. Varlamov, N. D. Sergeeva, A. T. Soldatenkov, O. V. Zvolinskii, A. A. Astakhov, and N. S. Prostakov, Khim. Geterotsikl. Soedin., 973 (1987).Google Scholar
  5. 5.
    N. S. Prostakov, A. V. Varlamov, T. N. Borisova, and N. D. Sergeeva, Khim. Geterotsikl. Soedin., 1287 (1987).Google Scholar
  6. 6.
    B. A. Trofimov, S. E. Korostova, L. N. Balabanova, and A. I. Mikhaleva, Zh. Org. Khim., 14, 1733 (1978).Google Scholar
  7. 7.
    S. E. Korostova, L. N. Sobenina, L. N. Nesterenko, I. A. Aliev, and A. I. Mikhaleva, Zh. Org. Khim., 20, 1960 (1984).Google Scholar
  8. 8.
    B. A. Trofimov, S. E. Korostova, L. N. Balabanova, and A. I. Mikhaleva, Khim. Geterotsikl. Soedin., 489 (1978).Google Scholar
  9. 9.
    S. E. Korostova, S. G. Shevchenko, and M. V. Sigalov, Khim. Geterotsikl. Soedin., 187 (1991).Google Scholar
  10. 10.
    S. E. Korostova, A. I. Mikhaleva, L. N. Sobenina, S. G. Shevchenko, and V. V. Sherbanov, Khim. Geterotsikl. Soedin., 1501 (1985).Google Scholar
  11. 11.
    S. E. Korostova, S. G. Shevchenko, E. A. Polubeshchev, A. I. Mikhaleva, and B. A. Trofimov, Khim. Geterotsikl. Soedin., 770 (1989).Google Scholar
  12. 12.
    N. S. Vul'fson, V. G. Zaikin, and A. I. Mikaya, Mass Spectrometry of Organic Compounds [in Russian], Khimiya, Moscow (1986).Google Scholar
  13. 13.
    P. Gautzel and T. Krueblood, Acta Crystallogr., 18, 958 (1965).Google Scholar
  14. 14.
    M. Sheehan and D. Y. Gram, J. Am. Chem. Soc., 91, 3953 (1969).Google Scholar
  15. 15.
    G. M. Sheldrick, SHELXS 86. Program for the Solution of Crystal Structures. Univ. of Göttingen, Göttingen, Germany (1985).Google Scholar
  16. 16.
    G. M. Sheldrick, SHELXS 93. Program for the Refinement of Crystal Structures. Univ. of Göttingen, Göttingen, Germany(1993).Google Scholar

Copyright information

© Plenum Publishing Corporation 2004

Authors and Affiliations

  • A. V. Varlamov
    • 1
  • T. N. Borisova
    • 1
  • Boniface Nsabimana
    • 1
  • A. I. Chernyshev
    • 1
  • G. G. Aleksandrov
    • 1
  • L. G. Voskressensky
    • 1
  1. 1.Russian People's Friendship UniversityMoscow

Personalised recommendations