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Phenyliodonium Derivatives of N-Heterocycles and CH-Acids, Their Synthesis, and Their Use in the Chemistry of Heterocycles. (Review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reactions of iodosylbenzene with CH-acids, including β-dicarbonyl and N-heterocyclic compounds in the presence of alkali, which lead to the aryliodonium ylides (betaines) used in the synthesis of new derivatives of heterocycles, are examined. Both β-dicarbonyl compounds and the anions of various heterocyclic compounds (pyrrole, indole, pyrazolidinedione, hydroxypyrones, hydroxypyridones, oxo- and dioxopyrimidines) and β-keto sulfones, β-disulfones, cyclopentadienes, and malononitrile enter into the reaction.

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  1. Riga Technical University, Riga, LV-1048, Latvia

    O. Neilands

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Neilands, O. Phenyliodonium Derivatives of N-Heterocycles and CH-Acids, Their Synthesis, and Their Use in the Chemistry of Heterocycles. (Review). Chemistry of Heterocyclic Compounds 39, 1555–1569 (2003). https://doi.org/10.1023/B:COHC.0000018332.75425.5b

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