Abstract
Using quantum-chemical calculations we have carried out an analysis of frontier molecular orbital interactions in the [2+3] cycloaddition reactions of C,C,N-triphenyl- and Z-C,N-diphenylnitrones with β- and α-substituted nitroethylenes. In all of the examples studied the orbital effects lead to the formation of the corresponding 4-nitroisoxazolidines.
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Jasinski, R., Ciezkowska, A., Lyubimtsev, A. et al. Synthesis and Properties of Azoles and Their Derivatives. 54. The Regioselectivity of [2+3] Cycloaddition Of C,C,N-Triphenyl- and Z-C,N-Diphenylnitrones With β- and α-Substituted Nitroethylenes in Light of Frontier Molecular Orbital Theory. Chemistry of Heterocyclic Compounds 40, 203–210 (2004). https://doi.org/10.1023/B:COHC.0000027893.83553.c2
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DOI: https://doi.org/10.1023/B:COHC.0000027893.83553.c2