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Reaction of 5-Hydrazono-1,2,3-thiadiazoles with Toluene and Xylene in the Presence of PCl5

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The treatment of 5-hydrazono-1,2,3-thiadiazoles by phosphorus pentachloride in toluene or xylene leads to an anomalous Dimroth rearrangement and the reaction of the mercapto function formed with the methyl group of the solvent to give 5-benzylmercapto-1,2,3-triazole.

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Authors and Affiliations

  1. Urals State Technical University, Yekaterinburg, 620002, Russia

    T. V. Glukhareva, L. V. Dyudya, Yu. Yu. Morzherin & V. A. Bakulev

  2. Novosibirsk Institute of Organic Chemistry, Novosibirsk, 630090, Russia

    A. V. Tkachev

Authors
  1. T. V. Glukhareva
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  2. L. V. Dyudya
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  3. Yu. Yu. Morzherin
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  4. A. V. Tkachev
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  5. V. A. Bakulev
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Glukhareva, T.V., Dyudya, L.V., Morzherin, Y.Y. et al. Reaction of 5-Hydrazono-1,2,3-thiadiazoles with Toluene and Xylene in the Presence of PCl5 . Chemistry of Heterocyclic Compounds 39, 126–127 (2003). https://doi.org/10.1023/A:1023041329732

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  • DOI: https://doi.org/10.1023/A:1023041329732

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