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The Kornblum Reaction of α-Substituted 3-Benzyl-1,2-dihydro-2-oxoquinoxalines. Synthesis and Structure of 3-Benzoyl-2-oxo-1,2-dihydroquinoxaline

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method has been developed for the preparation of 3-benzoyl-2-oxo-1,2-dihydroquinoxaline by the reaction of 3-(α-chlorobenzyl)-1,2-dihydroquinoxaline under Kornblum reaction conditions to the corresponding α-azido derivative and then acid fission of the latter. The structure of the target ketone has been confirmed by X-ray analysis.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan, 420088, Russia

    V. A. Mamedov, A. A. Kalinin, A. T. Gubaidullin, I. A. Litvinov & Ya. A. Levin

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  1. V. A. Mamedov
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  2. A. A. Kalinin
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  3. A. T. Gubaidullin
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  4. I. A. Litvinov
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  5. Ya. A. Levin
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Mamedov, V.A., Kalinin, A.A., Gubaidullin, A.T. et al. The Kornblum Reaction of α-Substituted 3-Benzyl-1,2-dihydro-2-oxoquinoxalines. Synthesis and Structure of 3-Benzoyl-2-oxo-1,2-dihydroquinoxaline. Chemistry of Heterocyclic Compounds 38, 1504–1510 (2002). https://doi.org/10.1023/A:1022601829731

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  • DOI: https://doi.org/10.1023/A:1022601829731

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