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Photochemical Reactions in Gaseous Mixtures of C2F4 and CF3I

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Abstract

Products of photochemical reactions occurring in gaseous mixtures of C2F4 and CF3I under vacuum-UV irradiation were studied. The major photolysis products are linear perfluoroparaffins CnF2n+2 and linear perfluoroalkyl iodides CnF2n+2I. The product ratio is consistent with the suggested kinetic scheme of chain reactions of telomers.

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Authors and Affiliations

  1. Prikladnaya Khimiya Russian Scientific Center, St. Petersburg, Russia

    V. P. Fokanov, A. B. Pavlov, V. N. Semenov & A. V. Morozov

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  1. V. P. Fokanov
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  2. A. B. Pavlov
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  3. V. N. Semenov
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  4. A. V. Morozov
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Fokanov, V.P., Pavlov, A.B., Semenov, V.N. et al. Photochemical Reactions in Gaseous Mixtures of C2F4 and CF3I. Russian Journal of Applied Chemistry 75, 1444–1447 (2002). https://doi.org/10.1023/A:1022280913143

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