Abstract
The sol-gel process of the preparation of globular zirconium(IV) hydroxide is described, which involves formation of zirconium(IV) hydroxide sol by electrolysis of zirconium(IV) chloride solution in a one-compartment cell to a Cl/Zr atomic ratio of less than 0.6, gelation of sol droplets in aqueous ammonia, treatment of gel spheres to remove electrolytes, and drying.
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Sharygin, L.M. Preparation of Globular Zirconium(IV) Hydroxide by Sol-Gel Process. Russian Journal of Applied Chemistry 75, 1394–1398 (2002). https://doi.org/10.1023/A:1022256307691
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DOI: https://doi.org/10.1023/A:1022256307691