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Mechanism of Cyclohexane Ozonolysis Considering Alternative Pathways

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Abstract

Ozonolysis of cyclohexane was considered taking into account the alternative pathway of recombination of peroxy radicals to form cyclohexanol and cyclohexanone. The rate constants of the reactions involved were determined experimentally or by calculations (optimization of the process model).

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REFERENCES

  1. Syroezhko, A.M., Proskuryakov, V.A., and Begak, O.Yu., Zh. Prikl. Khim., 2002, vol. 75, no. 8, pp. 1320-1328.

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  2. Maslennikov, S.I., Galimova, L.G., and Komissarov, V.D., Izv. Akad. Nauk SSSR, Ser. Khim., 1979, no. 3, pp. 631-634.

  3. Korotkova, N.P., Oxidation of Cyclohexane and Some Oxygen-Containing Compounds with Ozone-Air Mixtures, Cand. Sci. Dissertation, Leningrad, 1978.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, St. Petersburg, Russia

    A. M. Syroezhko, V. A. Proskuryakov & O. Yu. Begak

  2. Federal State Unitary Enterprise, Mendeleev Russian Research Institute of Metrology, St. Petersburg, Russia

    A. M. Syroezhko, V. A. Proskuryakov & O. Yu. Begak

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  1. A. M. Syroezhko
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  2. V. A. Proskuryakov
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  3. O. Yu. Begak
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Syroezhko, A.M., Proskuryakov, V.A. & Begak, O.Y. Mechanism of Cyclohexane Ozonolysis Considering Alternative Pathways. Russian Journal of Applied Chemistry 75, 1448–1452 (2002). https://doi.org/10.1023/A:1022233129981

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  • DOI: https://doi.org/10.1023/A:1022233129981

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