Skip to main content
SpringerLink
Log in

Molecular structure and absolute configuration of (+)-(1R, 2S, 6R, 7S, 1′R)-5-(1′-phenylethylamino)-endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The crystal and molecular structure of (+)-(1R, 2S, 6R, 7S, 1′R)-5-(1′-phenylethylamino)-endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one is described. Based on the known absolute configuration (R) of the α-phenylethylamine moiety the X-ray analysis revealed the absolute configuration of the title compound. The structure was refined to R 1 = 0.0298 for 1950 reflections (with I > 2σ(I)). Crystal data: C18H19NO, monoclinic, space group P21, a = 6.7406(4), b = 9.959(2), c = 11.3123(8)Å, β = 102.969(5), V = 740.0(2)Å3, and Z = 2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zhu, J.; Yang, J.Y.; Klunder, A.J.H.; Liu, Z.Y.; Zwanenburg, B. Tetrahedron 1995, 51, 5847, and references cited therein.

    Google Scholar 

  2. Bakkeren, F.J.A.D.; Ramesh, N.G.; De Groot, D.; Klunder; A.J.H.; Zwanenburg, B. Tetrahedron Lett. 1996, 37, 8003.

    Google Scholar 

  3. Gelder, R. de; Graaff, R.A.G. de; Schenk, H. Acta Crystallogr. 1993, A49, 287.

    Google Scholar 

  4. Spek, A.L. Acta Crystallogr. 1990, A46, C-34.

    Google Scholar 

  5. North, A.C.T.; Philips, D.C.; Mathews, F.S. Acta Crystallogr. 1968, A24, 351.

    Google Scholar 

  6. Sheldrick, G.M. SHELXL-93. Program for the Refinement of Crystal Structures; University of Gottingen: Germany, 1993.

    Google Scholar 

  7. Spek, A.L. PLATON-93. Program for Display and Analysis of Crystal and Molecular Structures; University of Utrecht: The Netherlands, 1995.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Nijmegen SON Research Center, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands

    René de Gelder & Jan M. M. Smits

  2. Department of Organic Chemistry, Nijmegen SON Research Center, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands

    Namakkal G. Ramesh, Frank J. A. D. Bakkeren, Debby de Groot & Antonius J. H. Klunder

Authors
  1. René de Gelder
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jan M. M. Smits
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Namakkal G. Ramesh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Frank J. A. D. Bakkeren
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Debby de Groot
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Antonius J. H. Klunder
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

de Gelder, R., Smits, J.M.M., Ramesh, N.G. et al. Molecular structure and absolute configuration of (+)-(1R, 2S, 6R, 7S, 1′R)-5-(1′-phenylethylamino)-endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one. Journal of Chemical Crystallography 28, 497–499 (1998). https://doi.org/10.1023/A:1021733108852

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021733108852

Search

Navigation