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Trimethylene-bridged Tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn(CH2)3Sn(OOCR)CH2SiMe3]O}n (R = Ph, 2,4-Me2C6H3): Control of Structure by Variation of R

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The synthesis of trimethylene-bridged carboxylate-substituted tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn(CH2)3Sn(OOCR)CH2SiMe3]O} n (1, R = Ph; 2, R = 2,4-Me2C6H3) is reported. Depending on the structure of R, in the solid state these compounds are either dimers (1, n = 2, cis-isomer) with a ladder-type structure or tetramers (2, n = 4) with a double ladder-type structure.

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Authors and Affiliations

  1. Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund, D-44221, Dormund, Germany

    B. Costisella, K. Jurkschat, M. Mehring, I. Paulus & M. Sch¨rmann

  2. Centre for Chiral and Molecular Technologies, Deakin University, Geelong, Victoria, 3217, Australia

    D. Dakternieks

Authors
  1. B. Costisella
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  2. D. Dakternieks
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  3. K. Jurkschat
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  4. M. Mehring
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  5. I. Paulus
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  6. M. Sch¨rmann
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Costisella, B., Dakternieks, D., Jurkschat, K. et al. Trimethylene-bridged Tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn(CH2)3Sn(OOCR)CH2SiMe3]O}n (R = Ph, 2,4-Me2C6H3): Control of Structure by Variation of R. Chemistry of Heterocyclic Compounds 37, 1405–1417 (2001). https://doi.org/10.1023/A:1017907419300

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