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Adsorption of Complexes of Cations of Alkali Metals with a Macrocyclic Ligand (Kryptofix® 222) on a Mercury Electrode

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Abstract

Adsorption of complexes of alkali metal cations with a macrocyclic ligand (C18H36N2O6, Kryptofix® 222) is studied as a function of their concentration by measuring the differential capacitance on a stationary mercury drop. The complexes (kryptates) possess a high adsorption capability. The adsorption parameters of sodium kryptate are found within a model of two parallel capacitors complemented by a Frumkin adsorption isotherm. Curves of the differential capacitance and the electrocapillary curves, calculated from these parameters, nicely conform to the experimental data obtained in this work and to the literature data.

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REFERENCES

  1. Dietrich, B., Lehn, J.M., and Sauvage, J.P., Tetrahedron Lett., 1969, no. 34, p. 2885.

  2. Cox, B.G., Garcia-Rosas, J., and Schnaider, H., J. Am. Chem. Soc., 1981, vol. 103, p. 1384.

    Google Scholar 

  3. Lehn, J.M., Pure Appl. Chem., 1980, vol. 52, p. 2303.

    Google Scholar 

  4. Carla, M., Gambi, C.M.C., and Baglioni, P., J. Phys. Chem., 1996, vol. 100, p. 11067.

    Google Scholar 

  5. Stenina, E.V., Baturina, O.A., Sviridova, L.N., and Damaskin, B.B., Elektrokhimiya, 2001, vol. 37, p. 1084.

    Google Scholar 

  6. Stenina, E.V., Damaskin, B.B., Fedorovich, N.V., and Dyatkina, S.L., Dokl. Akad. Nauk SSSR, 1977, vol. 236, p. 400.

    Google Scholar 

  7. Frumkin, A.N., Z. Phys. Chem. (Leipzig), 1925, vol. 116, p. 466.

    Google Scholar 

  8. Frumkin, A.N., Z. Phys., 1926, vol. 35, p. 792.

    Google Scholar 

  9. Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Adsorption of Organic Compounds on Electrodes), Moscow: Nauka, 1968, Chap. III.

    Google Scholar 

  10. Damaskin, B.B., Safonov, V.A., and Baturina, O.A., Elektrokhimiya, 1995, vol. 31, p. 856; 1997, vol. 33, p. 117.

    Google Scholar 

  11. Stenina, E.V., Baturina, O.A., Sviridova, L.N., and Damaskin, B.B., Elektrokhimiya, 1999, vol. 35, p. 1485.

    Google Scholar 

  12. Alekseev, Yu.V., Popov, Yu.A., and Kolotyrkin, Ya.M., Elektrokhimiya, 1976, vol. 12, p. 907.

    Google Scholar 

  13. Damaskin, B.B. and Baturina, O.A., Elektrokhimiya, 1998, vol. 34, p. 611; 1999, vol. 35, p. 1348; 2001, vol. 37, p. 87.

    Google Scholar 

  14. Damaskin, B.B., Baturina, O.A., and Safonov, V.A., Elektrokhimiya, 2000, vol. 36, p. 1319.

    Google Scholar 

  15. Damaskin, B.B., Safonov, V.A., and Dyatkina, S.L., Elektrokhimiya, 1986, vol. 22, p. 308.

    Google Scholar 

  16. Grahame, D.C., J. Electrochem. Soc., 1951, vol. 98, p. 343.

    Google Scholar 

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Authors and Affiliations

  1. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    E. V. Stenina, O. A. Baturina, L. N. Sviridova & B. B. Damaskin

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  1. E. V. Stenina
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  2. O. A. Baturina
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  3. L. N. Sviridova
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  4. B. B. Damaskin
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Stenina, E.V., Baturina, O.A., Sviridova, L.N. et al. Adsorption of Complexes of Cations of Alkali Metals with a Macrocyclic Ligand (Kryptofix® 222) on a Mercury Electrode. Russian Journal of Electrochemistry 38, 602–607 (2002). https://doi.org/10.1023/A:1016094216289

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