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Derivatives of sym-Triazine. 1. Synthesis and Conversions of Quaternary Methylammonium Salts of 2-Chloro-4,6-disubstituted 1,3,5-Triazines in Nucleophilic Substitution Reactions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

New quaternary ammonium salts of monochloro-4,6-disubstituted 1,3,5-triazines have been obtained. These compounds are convenient synthons for the synthesis of new cyano, alkoxy, and other derivatives of sym-triazine. Some conversions of the synthesized salts have been studied. An elimination-isomerization reaction of the sym-triazine ring into a 2-oxo-1,2-dihydro-sym-triazine ring was discovered.

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Authors and Affiliations

  1. Kuban State Agricultural University, Krasnodar, 350044, Russia

    A. A. Chesniuk, S. N. Mikhailichenko, V. S. Zavodnov & V. N. Zaplishny

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  1. A. A. Chesniuk
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  2. S. N. Mikhailichenko
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  3. V. S. Zavodnov
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  4. V. N. Zaplishny
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Chesniuk, A.A., Mikhailichenko, S.N., Zavodnov, V.S. et al. Derivatives of sym-Triazine. 1. Synthesis and Conversions of Quaternary Methylammonium Salts of 2-Chloro-4,6-disubstituted 1,3,5-Triazines in Nucleophilic Substitution Reactions. Chemistry of Heterocyclic Compounds 38, 177–182 (2002). https://doi.org/10.1023/A:1015335124677

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  • DOI: https://doi.org/10.1023/A:1015335124677

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