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Homolytic Addition Reaction of Vinylsulfonylfluorobenzene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 3,6-bis(vinylsulfonyl)-1,2,4,5-tetrafluorobenzene with a large excess of tetrahydrofuran at 50-55°C gives the homolytic addition product 3,6-bis[2-(2-tetrahydrofuryl)ethylsulfonyl]-1,2,4,5-tetrafluorobenzene. The reaction is effected by peroxides radical process initiators obtained by the autooxidation of tetrahydrofuran.

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Amosova, S.V., Gavrilova, G.M., Gostevskaya, V.I. et al. Homolytic Addition Reaction of Vinylsulfonylfluorobenzene. Chemistry of Heterocyclic Compounds 38, 35–39 (2002). https://doi.org/10.1023/A:1014895023883

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  • DOI: https://doi.org/10.1023/A:1014895023883

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