Abstract
Reaction of benzoylacetylene with 1,5-diphenyldithiobiuret in glacial AcOH in the presence of equimolar amounts of HClO4 leads exclusively to 2-benzoylmethyl-4,6-di(phenylimino)-1,3,5-dithiazinium perchlorate. In MeOH, benzene, and MeCN medium, the reaction proceeds nonselectively and a mixture is formed that includes 2-benzoylmethyl-4,6-di(phenylimino)-1,3,5-dithiazine, 2-benzoylmethyl-4-benzoylvinylthio-3-phenyl-6-phenylimino-1,3,5-thiadiazine, 2-benzoylmethyl-4,6-di-(thiocarbonyl)-1,3-diphenyl-1,3,5-triazine, and N-benzoylvinyl-N'-phenylthiourea.
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REFERENCES
A. E. S. Fairfull and D. A. Peak, J. Chem. Soc., 803 (1955).
M. S. Chande and N. P. Shetgiri, J. Ind. Chem. Soc., 67, 849 (1990).
P. P. Pathe and M. G. Paranjpe, Indian J. Chem. B., 20, 824 (1981).
P. P. Pathe and M. G. Paranjpe, J. Ind. Chem. Soc., 61, 149 (1984).
M. S. Chande, J. D. Bhandari, and A. S. Karyekar, Indian J. Chem. B., 34, 990 (1995).
C. P. Joshua, E. Prasannan, and S. K. Thomas, Austral. J. Chem., 34, 917 (1981).
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Glotova, T.E., Nakhmanovich, A.S., Albanov, A.I. et al. Structure of Products of Reaction between Benzoylacetylene and 1,5-Diphenyldithiobiuret. Chemistry of Heterocyclic Compounds 38, 74–78 (2002). https://doi.org/10.1023/A:1014859410679
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DOI: https://doi.org/10.1023/A:1014859410679