Abstract
Results have been generalized for investigations on the synthesis of 1,2-thiaphosphacyclanes by intramolecular P=S alkylation of ω-haloalkyl substituted compounds of four-coordinated phosphorus with a P=S bond. The method has been extended to nitrogen-containing analogs with a P=N bond. A new general method is proposed for the synthesis of 1,2-thia- and 1,2-azaphosphacyclanes.
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Aladzheva, I.M., Bykhovskaya, O.V., Lobanov, D.I. et al. Intramolecular P=S and P=N Alkylation. General Method for Synthesizing 1,2-Heteraphosphacyclanes. Chemistry of Heterocyclic Compounds 38, 95–105 (2002). https://doi.org/10.1023/A:1014815628426
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DOI: https://doi.org/10.1023/A:1014815628426