Abstract
2,3'-Biquinolyl dianion reacts with organolithium and organomagnesium compounds with the formation, after treatment of the reaction mixture with water, of 2'-alkyl(aryl)-1',2'-dihydro-2,3'-biquinolyls, and, after treatment of the reaction mixture with alkyl halides, of 1'-alkyl-2'-alkyl(aryl)-1',2'-dihydro-2,3'-biquinolyls. The reaction includes attack of the nucleophilic reagent with an electron transfer to a molecule of solvent.
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Aksenov, A.V., Aksenova, I.V. & Smushkevich, Y.I. Investigations on 2,3'-Biquinolyls. 12. Alkylation and Arylation of 2,3'-Biquinolyl Dianion with Organometallic Compounds. New Type of Reaction for Dianions of Aromatic Compounds. Chemistry of Heterocyclic Compounds 37, 976–981 (2001). https://doi.org/10.1023/A:1012735500872
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DOI: https://doi.org/10.1023/A:1012735500872