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Electrical and Optical Properties of the Nitramine Group and Molecular Structure of Some N-Nitramines

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Abstract

The electrical and optical properties (dipole moment, electrooptical and optical Kerr constants, molecular polarizability anisotropy, polarizability tensor, molecular refraction) of N,N-dimethylnitramine as the simplest N-NO2 derivative were studied by a set of experimental and theoretical methods with the aim to determine the components of the polarizability ellipsoid of the N-NO2 group and develop a valence-optical scheme for calculating the optical and electrooptical parameters of N-NO2 compounds. Conjugation of the p electrons of the imide nitrogen atom with the π electrons of the nitro group results in deviation of the properties of N,N-dimethylnitramine from the additive values. Comparative evaluation of the parameters of the Csp3-NO2, Csp2-NO2, and N-NO2 groups was made.

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Authors and Affiliations

  1. Kharkov State Polytechnic University, Kharkov, Ukraine

    V. V. Prezhdo, A. S. Bykova, Z. Daszkiewicz, M. Halas, I. Iwaszkiewicz-Kostka, O. V. Prezhdo, J. Kyziol & Z. Blaszczak

  2. Pedagogical Institute, Kielce, Poland

    V. V. Prezhdo, A. S. Bykova, Z. Daszkiewicz, M. Halas, I. Iwaszkiewicz-Kostka, O. V. Prezhdo, J. Kyziol & Z. Blaszczak

  3. Opole University, Opole, Poland

    V. V. Prezhdo, A. S. Bykova, Z. Daszkiewicz, M. Halas, I. Iwaszkiewicz-Kostka, O. V. Prezhdo, J. Kyziol & Z. Blaszczak

  4. Mickiewicz University, Poznan, Poland

    V. V. Prezhdo, A. S. Bykova, Z. Daszkiewicz, M. Halas, I. Iwaszkiewicz-Kostka, O. V. Prezhdo, J. Kyziol & Z. Blaszczak

  5. Washington University, Seattle, United States

    V. V. Prezhdo, A. S. Bykova, Z. Daszkiewicz, M. Halas, I. Iwaszkiewicz-Kostka, O. V. Prezhdo, J. Kyziol & Z. Blaszczak

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  1. V. V. Prezhdo
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Prezhdo, V.V., Bykova, A.S., Daszkiewicz, Z. et al. Electrical and Optical Properties of the Nitramine Group and Molecular Structure of Some N-Nitramines. Russian Journal of General Chemistry 71, 907–916 (2001). https://doi.org/10.1023/A:1012383418868

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