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Exciton Coupling and Complexation Behaviour of β-Cyclodextrin Naphthoate

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Abstract

The host–guest complexation behaviour ofβ-cyclodextrin 6-O-mono-2-naphthoate(1) and 6-[(N-2-naphthoyl-2-aminoethyl) amino]-6-deoxy-β-cyclodextrin (2) have been studied by the circular dichroism method. The exciton coupling band of 1 suggests that two naphthoyl moieties are partly included in one β-CD cavity. Host 1 could form a dimer in a more polar solvent and the dimer could be dissociated in a less polar solvent or by adding a guest. Solvent-induced, concentrationinduced, and guest-induced circular dichroism variations were examined. No exciton coupling was observed for host 2.

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Authors and Affiliations

  1. Department of Chemistry, Peking University, Beijing, 100871, China

    Xing-Ming Gao & Yun-Hua Ye

  2. Department of Chemistry, Lanzhou University, Lanzhou, 730000, China

    Yan-Ling Zhang, Xue-Yi Ma & Wei-Sheng Liu

  3. Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou, 730000, China

    Lin-Hui Tong

  4. Department of Molecular Chemistry, Faculty of Engineering, Osaka University, 2-1Yamada-oka, Suita, 565-0871, Japan

    Yoshaihisa Inoue

Authors
  1. Xing-Ming Gao
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  2. Yan-Ling Zhang
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  3. Lin-Hui Tong
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  4. Yun-Hua Ye
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  5. Xue-Yi Ma
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  6. Wei-Sheng Liu
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  7. Yoshaihisa Inoue
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Gao, XM., Zhang, YL., Tong, LH. et al. Exciton Coupling and Complexation Behaviour of β-Cyclodextrin Naphthoate. Journal of Inclusion Phenomena 39, 77–80 (2001). https://doi.org/10.1023/A:1008199131354

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