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Reactions of 1-Trichloromethyl-2,4,6-trimethylbenzene with 2-Amino- and 2-Amino-5-bromopyridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new type of reaction has been discovered for trichloromethylarenes with pyridines. The reaction of 1-trichloromethyl-2,4,6-trimethylbenzene with 2-amino- and 2-amino-5-bromopyridines does not stop with formation of the pyridinium salt, but rather leads to unique amidines, namely, 1-[α-(2-pyridylimino)-2,4,6-trimethylbenzyl]-2-pyridonimine and its 5-bromo derivative.

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REFERENCES

  1. L. I. Belen'kii, I. S. Poddubnyi, and M. M. Krayushkin, Tetrahedron Lett., 36, 5075 (1995).

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  2. L. I. Belen'kii, I. S. Poddubnyi, and M. M. Krayushkin, Khim. Geterotsikl. Soedin., 830 (1995).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow

    I. S. Poddubnyi, L. I. Belen'kii & M. M. Krayushkin

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  1. I. S. Poddubnyi
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  2. L. I. Belen'kii
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  3. M. M. Krayushkin
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Poddubnyi, I.S., Belen'kii, L.I. & Krayushkin, M.M. Reactions of 1-Trichloromethyl-2,4,6-trimethylbenzene with 2-Amino- and 2-Amino-5-bromopyridines. Chemistry of Heterocyclic Compounds 36, 1169–1171 (2000). https://doi.org/10.1023/A:1002864531871

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  • DOI: https://doi.org/10.1023/A:1002864531871

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