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Some Reactions of Pyridinium Salts Derived from Trichloromethylarenes with N- and C-Nucleophiles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of N-(4-pyridyl)pyridinium and 4-chloropyridinium salts obtained from 1-trichloromethyl-2,4,6-trimethylbenzene and pyridine with N-nucleophiles such as piperidine and morpholine and with C-nucleophiles such as N,N-dimethylaniline and indole proceeds through hetarylation and gives the corresponding 4-substituted pyridines. N-(α,α-Dichlorobenzyl)pyridinium and N,N'-(α-chlorobenzylidene)bispyridinium salts obtained from trichloromethylbenzene do not undergo hetarylation.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia

    L. I. Belen'kii, I. S. Poddubnyi, S. I. Luiksaar & M. M. Krayushkin

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  1. L. I. Belen'kii
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  2. I. S. Poddubnyi
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  3. S. I. Luiksaar
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  4. M. M. Krayushkin
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Belen'kii, L.I., Poddubnyi, I.S., Luiksaar, S.I. et al. Some Reactions of Pyridinium Salts Derived from Trichloromethylarenes with N- and C-Nucleophiles. Chemistry of Heterocyclic Compounds 36, 1172–1176 (2000). https://doi.org/10.1023/A:1002816615941

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