Advertisement

Russian Journal of Applied Chemistry

, Volume 75, Issue 9, pp 1399–1405 | Cite as

Photostimulated Oxidation of Sn(II) in Aqueous Solutions: Spectral Sensitivity and Quantum Yield

  • O. V. Reva
  • T. N. Vorob'eva
Article
  • 41 Downloads

Abstract

The spectral sensitivity of Sn(II) complexes in acid and alkaline solutions of SnCl2 in photostimulated oxidation with oxygen was studied. The reaction mechanism was revealed. A spectrophotometric method for prompt monitoring of the composition of SnCl2 solutions was proposed.

Keywords

Oxidation Oxygen Aqueous Solution Quantum Yield Reaction Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    Shalkauskas, M. and Vashkyalis, A., Khimicheskaya metallizatsiya plastmass (Electroless Metal Plating of Plastics), Leningrad: Khimiya, 1985, 3rd ed.Google Scholar
  2. 2.
    Sviridov, V.V., Vorob'eva, T.N., Gaevskaya, T.V., and Stepanova, L.I., Khimicheskoe osaszhdenie metallov iz vodnykh rastvorov (Electroless Deposition of Metals from Aqueous Solutions), Sviridov, V.V., Ed., Minsk: Universitetskoe, 1987.Google Scholar
  3. 3.
    Schlesinger, M. and Feldstein, N., J. Electrochem. Soc., 1973, vol. 120, pp. 236-241.CrossRefGoogle Scholar
  4. 4.
    Dressik, W.J., Dulcey, C.S., Georger, J.H., et al., J. Electrochem. Soc., 1994, vol. 141, no. 1, pp. 210-220.CrossRefGoogle Scholar
  5. 5.
    Putten, A.M.T. van der and Bakker, J.W.G. de, J. Electrochem. Soc., 1993, vol. 40, no. 8, pp. 2221-2228.CrossRefGoogle Scholar
  6. 6.
    Reva, O.V. and Vorob'eva, T.N., Vestsi Akad. Navuk Bel., Ser. Khim. Navuk, 1995, no. 3, pp. 100-115.Google Scholar
  7. 7.
    Sard, R., J. Electrochem. Soc., 1970, vol. 117, pp. 864-870.CrossRefGoogle Scholar
  8. 8.
    Cohen, R.L., D'Amico, I.F., and West, K.W., J. Electrochem. Soc., 1971, vol. 118, pp. 2042-2046.CrossRefGoogle Scholar
  9. 9.
    Sharp, D.J., Plating, 1971, vol. 58, no. 8, pp. 786-790.Google Scholar
  10. 10.
    Reva, O.V., Vorob'eva, T.N., and Sviridov, V.V., Zh. Nauchn. Prikl. Fotogr. Kinematogr., 1999, vol. 44, no. 4, pp. 20-26.Google Scholar
  11. 11.
    Reva, O.V. and Vorob'eva, T.N., Zh. Prikl. Khim., 1998, vol. 71, no. 3, pp. 498-502.Google Scholar
  12. 12.
    Atkins, P.W., Physical Chemistry, Oxford: Oxford Univ. Press, 1994, 3rd ed.Google Scholar
  13. 13.
    Kutner, E. and Matseevskii, B., Kinet. Katal., 1969, vol. 10, no. 5, pp. 997-1003.Google Scholar
  14. 14.
    Zakharov, I., Karasevich, E., Shilov, A., and Shteinman, A., Kinet. Katal., 1975, vol. 14, no. 5, pp. 1151-1157.Google Scholar
  15. 15.
    Berentsveig, V., Pleskach, N., and Rudenko, A., Zh. Fiz. Khim., 1980, vol. 54, no. 12, pp. 222-236.Google Scholar
  16. 16.
    Razinkin, M., Berentsveig, V., and Rudenko, A., Vestn. Mosk. Gos. Univ., Ser. Khim., 1990, issue 31, no. 1, pp. 75387.Google Scholar
  17. 17.
    Petrite, L.I., Solutions of Palladium and Tin Compounds and Their Use in Electroless Metal Plating, Cand. Sci. Dissertation, Vilnius, 1981.Google Scholar
  18. 18.
    Paul, R.C., Sooch, K.S., Vaidya, O.S., and Narula, S.P., Anal. Chim. Acta, 1969, vol. 46, no. 1, pp. 131-137.CrossRefGoogle Scholar
  19. 19.
    Calvert, J.G. and Pitts, J.N., Photochemistry, New York: Wiley, 1966.Google Scholar
  20. 20.
    Spravochnik khimika (Chemist's Handbook), Nikol'skii, B.P., Ed., Moscow: Khimiya, 1966, vol. 5.Google Scholar
  21. 21.
    Klyuchnikov, N.G., Rukovodstvo po neorganicheskomu sintezu (Manual on Inorganic Synthesis), Moscow: Khimiya, 1965.Google Scholar
  22. 22.
    Baudler, M., Brauer, J., Feher, F., et al., Handbuch der pr1aparativen anorganischen Chemie, Stuttgart: Enke, 1975. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985, vol. 3, pp. 669-1056.Google Scholar
  23. 23.
    Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Bol'shaya Ross. Entsiklopediya, 1988, vol. 3.Google Scholar
  24. 24.
    Bohren, C.E. and Huffman, D.R., Absorption and Scattering of Light by Small Particles, New York: Wiley, 1983.Google Scholar
  25. 25.
    Reva, O.V., Chemical, Electrochemical, and Photochemical Transformations of Tin Compounds in Heterogeneous Systems, Cand. Sci. Dissertation, Minsk, 1999.Google Scholar
  26. 26.
    Vorob'eva, T.N., Barkovskaya, L.V., Stepanova, L.I., and Rukhlya, V.A., Vestsi Akad. Navuk Bel. SSR, Ser. Khim. Navuk, 1991, no. 5, pp. 106-111.Google Scholar
  27. 27.
    Vorob'eva, T.N., Reva, O.V., Rukhlya, V.A., et al., Vestsi Akad. Navuk Bel., Ser. Khim. Navuk, 1994, no. 2, pp. 94-100.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2002

Authors and Affiliations

  • O. V. Reva
    • 1
  • T. N. Vorob'eva
    • 1
  1. 1.Research Institute of Physicochemical ProblemsBelarussian State UniversityMinskBelarus

Personalised recommendations