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Effects of hydrogen ion implantation on TiC-C coating of stainless steel

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Abstract

Titanium carbide coatings are widely used as various wear-resistant material. The hydrogen erosion resistance of TiC-C films and the effect of hydrogen participation on TiC-C films were studied. Seventy-five percent TiC-C films are prepared on stainless steel surface by using ion mixing, where TiC-C films are deposited by rf magnetron sputtering followed by argon ion bombardment. The samples are then submitted to hydrogen ion implantation at 1.2 × 10−3 Pa. Characterization for the 75% TiC-C films was done with SIMS, XRD, AES, and XPS. Secondary ion mass spectroscopy (SIMS) was used to analyze hydrogen concentration variation with depth, X-Ray diffraction (XRD) was used to identify the phases, and Auger electron spectra (AES) as well as X-ray photoelectron spectra (XPS) were used to check the effects of hydrogen on shifts of chemical bonding states of C and Ti in the TiC-C films. It is found that TiC-C films on stainless steel surface can prevent hydrogen from entering stainless steel.

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Correspondence to Rui-qian Zhang.

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Foundation Item: Item Sponsored by National Natural Science Foundation of China (98061001); Foundation of the Institute of Engineering Physics of China (9603025)

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Zhang, Rq., Liu, Yg. & Huang, Nk. Effects of hydrogen ion implantation on TiC-C coating of stainless steel. J. Iron Steel Res. Int. 15, 77–81 (2008). https://doi.org/10.1016/S1006-706X(08)60148-X

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  • DOI: https://doi.org/10.1016/S1006-706X(08)60148-X

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