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RETRACTED ARTICLE: Nanostructures of chemically modified multi-walled carbon nanotubes and poly(3-hexylthiophene) to improve photophysic/photovoltaic features

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This article was retracted on 02 June 2022

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Abstract

Multi-walled carbon nanotube/poly(3-hexylthiophene) (CNT/P3HT) and CNT-graft-poly(3-dodecylthiophene) (PDDT)/P3HT nanohybrids were applied in active layers to study the effects of these nanostructures on the polymer solar cell (PSC) performance. The charge-carrier dynamics and photophysics were studied in the binary and ternary systems based on P3HT, pre-developed nanostructures and/or phenyl-C71-butyric acid methyl ester (PC71BM) through the electrochemical impedance spectroscopy and morphological analyses. The weaker bimolecular recombination in the photoactive layer, consisting of CNT-graft-PDDT/P3HT nanostructures, was confirmed by short-circuit current (Jsc) and open-circuit voltage (Voc) measurements as a function of light intensity. PSC composed of P3HT:PC71BM:CNT-graft-PDDT/P3HT PSC exhibited the highest PCE of 4.18% with significantly increased Jsc and Voc.

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References

  1. Wang S-H, Hsiao Y-J, Fang T-H, Lin M-H, Kang S-H (2013) Enhancing performance and nanomechanical properties of carbon nanotube doped P3HT: PCBM solar cells. ECS J Solid State Sci Technol 2(11):M52–M55

    Article  CAS  Google Scholar 

  2. Yan J, Ni T, Zou F, Zhang L, Yang D, Yang S, Zou B (2014) Towards optimization of functionalized single-walled carbon nanotubes adhering with poly (3-hexylthiophene) for highly efficient polymer solar cells. Diam Relat Mater 41:79–83

    Article  CAS  Google Scholar 

  3. Huang B, Amonoo JA, Li A, Chen XC, Green PF (2014) Role of domain size and phase purity on charge carrier density, mobility, and recombination in poly (3-hexylthiophene): phenyl-C61-butyric acid methyl ester devices. J Phys Chem C 118(8):3968–3975

    Article  CAS  Google Scholar 

  4. Cakmak G, Guney HY, Yuksel SA, Gunes S (2015) The effect of functionalized single walled carbon nanotube with octadecylamine on efficiency of poly-(3-hexylthiophene):[(6, 6)] phenyl C61 butyric acid methyl ester organic solar cells. Phys B 461:85–91

    Article  CAS  Google Scholar 

  5. Rathore P, Negi CMS, Yadav A, Verma AS, Gupta SK (2018) Influence of MWCNT doping on performance of polymer bulk heterojunction based devices. Optik 160:131–137

    Article  CAS  Google Scholar 

  6. Cataldo S, Salice P, Menna E, Pignataro B (2012) Carbon nanotubes and organic solar cells. Energy Environ Sci 5(3):5919–5940

    Article  CAS  Google Scholar 

  7. Keru G, Ndungu PG, Nyamori VO (2014) A review on carbon nanotube/polymer composites for organic solar cells. Int J Energy Res 38(13):1635–1653

    Article  CAS  Google Scholar 

  8. Punetha VD, Rana S, Yoo HJ, Chaurasia A, McLeskey JT Jr, Ramasamy MS, Sahoo NG, Cho JW (2017) Functionalization of carbon nanomaterials for advanced polymer nanocomposites: a comparison study between CNT and graphene. Prog Polym Sci 67:1–47

    Article  CAS  Google Scholar 

  9. Van Le T, Nguyen TA, Nguyen NMT, Luu AT, Nguyen L-T, Nguyen HT (2016) Synthesis and characterization of nanocomposites based on poly (3-hexylthiophene)-graft-carbon nanotubes with LiNi 0.5 Mn 1.5 O 4 and its application as potential cathode materials for lithium-ion batteries. Bull Mater Sci 39(5):1177–1184

    Article  CAS  Google Scholar 

  10. Nogueira AF, Lomba BS, Soto-Oviedo MA, Correia CRD, Corio P, Furtado CA, Hümmelgen IA (2007) Polymer solar cells using single-wall carbon nanotubes modified with thiophene pedant groups. J Phys Chem C 111(49):18431–18438

    Article  CAS  Google Scholar 

  11. An CJ, Lee YC, Kang YH, Cho SY (2017) Improved interaction between semiconducting polymer and carbon nanotubes in thermoelectric composites through covalent grafting. Carbon 124:662–668

    Article  CAS  Google Scholar 

  12. Challa V, Nune K, Misra R (2016) The impact of molecular weight on nanoscale supramolecular structure of semiconducting poly (3-hexylthiophene) on carbon nanotubes and photophysical properties. Mater Technol 31(8):477–481

    Article  CAS  Google Scholar 

  13. Kadem B, Hassan A, Göksel M, Basova T, Şenocak A, Demirbaş E, Durmuş M (2016) High performance ternary solar cells based on P3HT: PCBM and ZnPc-hybrids. RSC Adv 6(96):93453–93462

    Article  CAS  Google Scholar 

  14. Wang D, Zhang X, Liu Y, Li L, Bo Z, Zhou J, Huo H (2017) Structure difference of sorbitol derivatives influences the crystallization and performance of P3OT/PCBM organic photovoltaic solar cells. Org Electron 46:158–165

    Article  CAS  Google Scholar 

  15. Singh V, Arora S, Arora M, Sharma V, Tandon R (2014) Optimizing P3HT/PCBM/MWCNT films for increased stability in polymer bulk heterojunction solar cells. Phys Lett A 378(41):3046–3054

    Article  CAS  Google Scholar 

  16. Mahakul PC, Sa K, Das B, Mahanandia P (2017) Structural investigation of the enhanced electrical, optical and electrochemical properties of MWCNT incorporated Poly [3-hexylthiophene-2, 5-diyl] composites. Mater Chem Phys 199:477–484

    Article  CAS  Google Scholar 

  17. Huang Y-C, Tsao C-S, Chuang C-M, Lee C-H, Hsu F-H, Cha H-C, Chen C-Y, Lin T-H, Su C-J, Jeng U-S (2012) Small-and wide-angle X-ray scattering characterization of bulk heterojunction polymer solar cells with different fullerene derivatives. J Phys Chem C 116(18):10238–10244

    Article  CAS  Google Scholar 

  18. Kim J, Park SY, Han G, Chae S, Song S, Shim JY, Bae E, Kim I, Kim HJ, Kim JY (2016) Conjugated polymers containing 6-(2-thienyl)-4H-thieno [3, 2-b] indole (TTI) and isoindigo for organic photovoltaics. Polymer 95:36–44

    Article  CAS  Google Scholar 

  19. Bakour A, Geschier F, Baitoul M, Wéry J, Massuyeau F, Faulques E (2016) Photoexcitations in fully organic nanocomposites of poly (3-hexylthiophene) and multiwalled carbon nanotubes. Mater Chem Phys 171:83–90

    Article  CAS  Google Scholar 

  20. Ramani R, Alam S (2013) A comparative study on the influence of alkyl thiols on the structural transformations in P3HT/PCBM and P3OT/PCBM blends. Polymer 54(25):6785–6792

    Article  CAS  Google Scholar 

  21. Liao X, Yao Z, Gao K, Shi X, Zuo L, Zhu Z, Chen L, Liu F, Chen Y, Jen AKY (2018) Mapping nonfullerene acceptors with a novel wide bandgap polymer for high performance polymer solar cells. Adv Energy Mater 8(24):1801214

    Article  CAS  Google Scholar 

  22. Salim T, Lee HW, Wong LH, Oh JH, Bao Z, Lam YM (2016) Semiconducting carbon nanotubes for improved efficiency and thermal stability of polymer–fullerene solar cells. Adv Func Mater 26(1):51–65

    Article  CAS  Google Scholar 

  23. Lin W-K, Su S-H, Yeh M-C, Huang Y-C, Yokoyama M (2015) Efficiency enhancement of solution-processed inverted organic solar cells with a carbon-nanotube-doped active layer. Jpn J Appl Phys 55(1S):01AE06

    Article  CAS  Google Scholar 

  24. Agbolaghi S, Charoughchi S, Aghapour S, Abbasi F, Bahadori A, Sarvari R (2018) Bulk heterojunction photovoltaics with improved efficiencies using stem-leaf, shish-kebab and double-fibrillar nano-hybrids based on modified carbon nanotubes and poly (3-hexylthiophene). Sol Energy 170:138–150

    Article  CAS  Google Scholar 

  25. Brinkmann M (2011) Structure and morphology control in thin films of regioregular poly (3-hexylthiophene). J Polym Sci, Part B: Polym Phys 49(17):1218–1233

    Article  CAS  Google Scholar 

  26. Stylianakis MM, Mikroyannidis JA, Kymakis E (2010) A facile, covalent modification of single-wall carbon nanotubes by thiophene for use in organic photovoltaic cells. Sol Energy Mater Sol Cells 94(2):267–274

    Article  CAS  Google Scholar 

  27. Somani SP, Somani PR, Umeno M, Flahaut E (2006) Improving photovoltaic response of poly (3-hexylthiophene)/n-Si heterojunction by incorporating double walled carbon nanotubes. Appl Phys Lett 89(22):223505

    Article  CAS  Google Scholar 

  28. Xing W, Chen Y, Wu X, Xu X, Ye P, Zhu T, Guo Q, Yang L, Li W, Huang H (2017) PEDOT: PSS-assisted exfoliation and functionalization of 2D nanosheets for high-performance organic solar cells. Adv Func Mater 27(32):1701622

    Article  CAS  Google Scholar 

  29. Sharma R, Lee H, Gupta V, Kim H, Kumar M, Sharma C, Chand S, Yoo S, Gupta D (2016) Photo-physics of PTB7, PCBM and ICBA based ternary solar cells. Org Electron 34:111–117

    Article  CAS  Google Scholar 

  30. Dennler G, Mozer AJ, Juška G, Pivrikas A, Österbacka R, Fuchsbauer A, Sariciftci NS (2006) Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells. Org Electron 7(4):229–234

    Article  CAS  Google Scholar 

  31. Roghabadi FA, Kokabi M, Ahmadi V, Abaeiani G (2016) Quantum dots crosslinking as a new method for improving charge transport of polymer/quantum dots hybrid solar cells and fabricating solvent-resistant film. Electrochim Acta 222:881–887

    Article  CAS  Google Scholar 

  32. Srivastava SB, Sonar P, Singh SP (2016) Analysis of degradation mechanisms in donor–acceptor copolymer based organic photovoltaic devices using impedance spectroscopy. Mater Res Express 3(9):096202

    Article  CAS  Google Scholar 

  33. Yang P, Zeigler D, Bryant K, Martin T, Gamelin D, Luscombe C (2014) Identifying effects of TiO 2 nanowires inside bulk heterojunction organic photovoltaics on charge diffusion and recombination. J Mater Chem C 2(25):4922–4927

    Article  CAS  Google Scholar 

  34. Somani SP, Somani PR, Umeno M (2008) Carbon nanotube incorporation: a new route to improve the performance of organic–inorganic heterojunction solar cells. Diam Relat Mater 17(4–5):585–588

    Article  CAS  Google Scholar 

  35. Somani PR, Somani SP, Flahaut E, Umeno M (2007) Improving the photovoltaic response of a poly (3-octylthiophene)/n-Si heterojunction by incorporating double-walled carbon nanotubes. Nanotechnology 18(18):185708

    Article  CAS  Google Scholar 

  36. Kong T, Wang H, Liu X, Yu J, Wang C (2016) Improving the efficiency of bulk heterojunction polymer solar cells via binary-solvent treatment. IEEE J Photovolt 7(1):214–220

    Article  Google Scholar 

  37. Wang K, Guo X, Ye C, Wang Y, Meng Y, Li X, Zhang M (2019) A new small-molecule donor containing non-fused ring π-bridge enables efficient organic solar cells with high open circuit voltage and low acceptor content. ChemPhysChem 20(20):2674–2682

    Article  CAS  Google Scholar 

  38. Lee TH, Park SY, Walker B, Ko S-J, Heo J, Woo HY, Choi H, Kim JY (2017) A universal processing additive for high-performance polymer solar cells. RSC Adv 7(13):7476–7482

    Article  CAS  Google Scholar 

  39. Niu S, Liu Z, Wang N (2018) Effect of titanium chelate as a function of thickness on the electron mobility and electron transport and collection efficiency. Sol Energy 159:458–464

    Article  CAS  Google Scholar 

  40. Liu L, Stanchina WE, Li G (2009) Performance analysis of bulk heterojunction solar cells fabricated by polymer: fullerene: carbon-nanotube composites. In: 2009 IEEE nanotechnology materials and devices conference, IEEE, pp 207–211

  41. Liu D, Kan B, Ke X, Zheng N, Xie Z, Lu D, Liu Y (2018) Extended conjugation length of nonfullerene acceptors with improved planarity via noncovalent interactions for high-performance organic solar cells. Adv Energy Mater 8(26):1801618

    Article  CAS  Google Scholar 

  42. Liu Z, Niu S, Wang N (2018) Light illumination intensity dependence of photovoltaic parameter in polymer solar cells with ammonium heptamolybdate as hole extraction layer. J Colloid Interface Sci 509:171–177

    Article  CAS  Google Scholar 

  43. Yan L, Yi J, Chen Q, Dou J, Yang Y, Liu X, Chen L, Ma C-Q (2017) External load-dependent degradation of P3HT: PC 61 BM solar cells: behavior, mechanism, and method of suppression. J Mater Chem A 5(20):10010–10020

    Article  CAS  Google Scholar 

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Correspondence to Mohammad Hossein Hekmatshoar, Farhang Abbasi or Samira Agbolaghi.

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This article has been retracted. Please see the retraction notice for more detail: https://doi.org/10.1007/s42823-022-00361-7

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Hadi, A., Hekmatshoar, M.H., Abbasi, F. et al. RETRACTED ARTICLE: Nanostructures of chemically modified multi-walled carbon nanotubes and poly(3-hexylthiophene) to improve photophysic/photovoltaic features. Carbon Lett. 31, 107–115 (2021). https://doi.org/10.1007/s42823-020-00155-9

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  • DOI: https://doi.org/10.1007/s42823-020-00155-9

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