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Emerging sorption pairs for heat pump applications: an overview

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Abstract

The research efforts to find an alternative system for the cooling/heating application have been intensified worldwide since the imposition of international restrictions on production and use of refrigerants accountable for ODP and GWP. Nowadays, the demand for the cooling/heating system is increased also due to safeguarding the adverse environmental effect which results in additional consumption of electrical energy and ecological problem. The use of adsorption system is considering as a promising alternative for the last few decades. The low heat and mass transfer coefficient of the adsorbent material is the main bottleneck of the adsorption cooling/heating system and resulting in large size and low performance. To make the system commercially competitive with the conventional system, high-performance refrigerant/adsorbent pairs are required. In this review, the favorable achievement in adsorbent development in terms of porous properties and their interaction with natural refrigerants is focused. Current application of different working pairs and their future prospect with special reference to their utilization are studied. Future research direction of adsorption working pairs is also analyzed.

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Abbreviations

A0 ~ A3 :

Adjustable parameter (−)

B0 ~ B3 :

Adjustable parameter (−)

\( b_{0} \) :

Equilibrium constant (kPa−1 or MPa−1)

\( c_{{{\text{p}},{\text{Ad}}}} \) :

Specific heat capacity of adsorbent (J g−1 K−1)

\( c_{{{\text{p}},{\text{ref}}}} \) :

Specific heat capacity of refrigerant (J g−1 K−1)

\( E \) :

Adsorption characteristic energy (kJ mol−1)

\( t \) :

Heterogeneity constant in Tóth equation (–)

h f :

Fluid enthalpy (kJ kg−1)

\( h_{\text{fg}} \) :

Latent heat of vaporization (kJ kg−1)

\( k \) :

Freundlich constant (–)

\( n \) :

Exponent of D-A equation (–)

\( P \) :

Pressure (kPa or MPa)

\( P_{\text{c}} \) :

Pressure at critical point (kPa or MPa)

\( P_{\text{s}} \) :

Saturation pressure (kPa or MPa)

\( Q \) :

Heat energy (J)

Q st :

Isosteric heat of adsorption (kJ kg−1)

\( q \) :

Volumetric adsorption uptake (cm3 g−1)

\( q_{0} \) :

Maximum volumetric adsorption capacity (cm3 g−1)

\( R \) :

Gas constant (J mol−1 K−1)

\( T \) :

Temperature (°C or K)

\( T_{\text{C}} \) :

Temperature at critical point (°C or K)

TPh:

Preheating temperature (°C)

\( V_{\text{m}} \) :

Molar volume (cm3 g−1)

v m :

Pore volume of the adsorbent (cm3 g−1)

V t :

Specific volume of liquid carbon dioxide (cm3 g−1)

\( W \) :

Equilibrium uptake (kg kg−1)

\( W_{0} \) :

Maximum equilibrium uptake (kg kg−1)

z :

Constant for pseudo saturated vapor pressure (−)

\( \alpha \) :

Thermal diffusivity (m2 s−1)

\( \alpha^{*} \) :

Thermal expansion of the adsorbed gas (K−1)

\( \rho \) :

Density (kg m−3)

\( \Delta W \) :

Effective uptake (–)

Ad:

Adsorbent

Ads:

Adsorption

Cond:

Condenser

Des:

Desorption

Eq:

Equilibrium

Evap:

Evaporator

Lat:

Latent heat

max:

Maximum

min:

Minimum

ref:

Refrigerant

s:

Saturation

sat:

Saturation

Sen:

Sensible

th:

Theoretical

Tot:

Total

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Acknowledgements

Authors acknowledge the International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Japan for the support.

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Authors and Affiliations

  1. International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan

    Bidyut Baran Saha, Kutub Uddin, Animesh Pal & Kyaw Thu

  2. Mechanical Engineering Department, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan

    Bidyut Baran Saha

  3. Faculty of Physics, Jagannath University, Dhaka, 1100, Bangladesh

    Kutub Uddin

  4. Kyushu University Program for Leading Graduate School, Green Asia Education Center, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Kasuga-koen 6-1, Kasuga-shi, Fukuoka, 816-8580, Japan

    Animesh Pal & Kyaw Thu

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  1. Bidyut Baran Saha
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Saha, B.B., Uddin, K., Pal, A. et al. Emerging sorption pairs for heat pump applications: an overview. JMST Adv. 1, 161–180 (2019). https://doi.org/10.1007/s42791-019-0010-4

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