Abstract
The graphene porous structure has attracted attention as an electrode material of an energy storage device because it has a high specific capacitance due to its excellent electrical properties and high surface area. This research suggests easy-to-fabricate graphene porous structure based on polymer sponge and graphene oxide (GO). The graphene sponge was made by hydrothermal synthesis of a polymer sponge and an aqueous dispersion of GO. The graphene sponge produced by inexpensive and simple method shows good electrochemical performance. Morphology and structural properties of graphene sponge were investigated by field effect scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction and Raman spectroscopy. The electrochemical performance was measured in 1 M KOH aqueous solution and showed good specific capacitance (214.06 F g−1) and ideal electric double-layer capacitor characteristics. This graphene sponge is flexible and can be applied to wearable devices and various next-generation energy storage devices.
References
Matthew J. Allen, Vincent C. Tung, Richard B. Kaner, Honeycomb carbon: a review of graphene. Chem. Rev. 110(1), 132–145 (2009)
L.L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38(9), 2520–2531 (2009)
A.G. Pandolfo, A.F. Hollenkamp, Carbon properties and their role in supercapacitors. J. Power Sources 157(1), 11–27 (2006)
K. Xia et al., Hierarchical porous carbons with controlled micropores and mesopores for supercapacitor electrode materials. Carbon 46(13), 1718–1726 (2008)
D.-W. Wang et al., Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode. ACS Nano. 3(7), 1745–1752 (2009)
Y. Xu et al., Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano. 4(7), 4324–4330 (2010)
F. Yavari et al., High sensitivity gas detection using a macroscopic three-dimensional graphene foam network. Sci Rep. 1, 166 (2011)
H. Bi et al., Spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents. Adv. Funct. Mater. 22(21), 4421–4425 (2012)
M. Łukaszewski, A. Żurowski, A. Czerwiński, Hydrogen in thin Pd-based layers deposited on reticulated vitreous carbon—a new system for electrochemical capacitors. J. Power Sources 185(2), 1598–1604 (2008)
X. Du et al., Graphene nanosheets as electrode material for electric double-layer capacitors. Electrochim. Acta. 55(16), 4812–4819 (2010)
D.C. Marcano et al., Improved synthesis of graphene oxide. ACS Nano. 4(8), 4806–4814 (2010)
Y. Qin et al., Lightweight, superelastic, and mechanically flexible graphene/polyimide nanocomposite foam for strain sensor application. ACS Nano. 9(9), 8933–8941 (2015)
D. Yang et al., Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy. Carbon. 47(1), 145–152 (2009)
K. Krishnamoorthy et al., The chemical and structural analysis of graphene oxide with different degrees of oxidation. Carbon. 53, 38–49 (2013)
L. Stobinski et al., GO and reduced GO studied by the XRD, TEM and electron spectroscopy methods. J. Electron Spectrosc. Relat. Phenom. 195, 145–154 (2014)
Y. Zhu et al., Graphene and GO: synthesis, properties, and applications. Adv. Mater. 22(35), 3906–3924 (2010)
L. Wang et al., Characteristics of Raman spectra for GO from ab initio simulations. J. Chem. Phys. 135(18), 184503 (2011)
N. Wu et al., Synthesis of network reduced GO in polystyrene matrix by a two-step reduction method for superior conductivity of the composite. J. Mater. Chem. 22(33), 17254–17261 (2012)
Adarsh Kaniyoor, Sundara Ramaprabhu, A Raman spectroscopic investigation of graphite oxide derived graphene. AIP Adv. 2(3), 032183 (2012)
I. Childres et al., Raman spectroscopy of graphene and related materials. New Dev. Photon Mater. Res. 1, 1–20 (2013)
X. Du et al., Graphene nanosheets as electrode material for electric double-layer capacitors. Electrochim. Acta. 55(16), 4812–4819 (2010)
S. Stankovich et al., Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon. 45(7), 1558–1565 (2007)
X. Xu et al., Facile synthesis of novel graphene sponge for high performance capacitive deionization. Sci. Rep. 5, 1–9 (2015)
S. Zhang, P. Ning, Supercapacitors performance evaluation. Adv. Energy Mater. 5(6), 1–19 (2015)
Acknowledgements
This subject is supported by Korea Ministry of Environment as “Global Top Project (2016002130005)” and Development of diagnostic system for mild cognitive impairment due to Alzheimer’s disease (2017-11-0951).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Seo, Y., Lee, S.C., Kang, J.S. et al. Preparation of graphene sponge with mechanical stability for compressible supercapacitor electrode. JMST Adv. 1, 81–87 (2019). https://doi.org/10.1007/s42791-019-0006-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42791-019-0006-0