Abstract
Transparent monolithic discs were obtained in presence of different surfactants: sodium dodecyl sulfate (SDS), ethanediyl-1,2-bis (dimethyldodecylammonium bromide (Gemini 12-2-12) or alkyl hydroxyethyl dimethyl ammonium chloride (HY). The use of surfactants has modified the morphology and porosity of the silica host matrix for better sensing properties. The entrapment of TB into silica matrix has shifted pKa value to more basic and less acidic. The presence of Gemini 12-2-12 and HY surfactants has shifted pKa value to more acidic, whereas SDS has shifted pKa to more basic in comparison with that of entrapped TB/silica.
Similar content being viewed by others
References
Aubonnet S, Barry HF, von Bultzingslowen C, Sabattie JM, MacCraith BD (2003) Photo-patternable optical chemical sensors based on hybrid sol–gel materials. Electron Lett 39:913–914
Frenkel-Mullerad Hagit, Avnir D (2005) Sol–gel materials as efficient enzyme protectors: preserving the activity of phosphatases under extreme pH conditions. J Am Chem Soc 127:8077–8081
Livage J, Coradin T, Roux C (2001) Encapsulation of biomolecules in silica gels. J Phys Condens 13:33
Miled OB, Grosso D, Sanches C, Livage J (2004) An optical fibre pH sensor based on dye doped mesostructured silica. J Phys Chem Solid 65:1751–1755
Rottman C, Grader G, Hazan YD, Melchior S, Avinir D (1999) Surfactant-induced modification of dopants reactivity in sol–gel matrixes. JACS 121:8533–8543
Brinker CJ, Scherer GW (1990) Sol–gel science, the physics and chemistry of sol–gel processing. Academic, San Diego
Tan J, Wang HF, Yan XP (2009) Discrimination of saccharides with a fluorescent molecular imprinting sensor array based on phenylboronic acid functionalized mesoporous silica. Anal Chem 81:5273–5280
Terry LA, White SF, Tigwell LJ (2005) The application of biosensors to fresh produce and the wider food industry. J Agric Food Chem 53:1309–1316
El-Nahhal IM, Zourab SM, Kodeh FS (2011) Encapsulation of bromothymol blue into a polysiloxane network matrix in presence of surfactants. J Dispers Sci Technol 32:1367–1370
El-Nahhal IM, Zourab SM, Kodeh FS (2014) Sol–gel encapsulation of bromothymol blue pH indicator in presence of Gemini 12-2-12 surfactant. J Sol-Gel Sci Technol 71:16–23
Shumaila I, Noriah B, Saira R, Shahzad N (2016) Sol–gel based phenolphthalein encapsulated heterogeneous silica–titania optochemical pH nanosensor. J Ind Eng Chem 34:258–268
Timbo AP, Pinho HA, Ferreira Pinto PV, de Moura LP, Chretien JB, Viana FW, Diogenes Filho RG, da Silva EB, Rodrigues da Silva ME, Menezes JW, de Freitas Guimaraes G, Fraga WB (2016) pH optical sensor based on thin films of sol–gel with bromocresol purple. Sens Actuators B Chem 223:406–414
Zhang J, Zhou L (2018) Preparation and optimization of optical pH sensors based on an organic carrier with four indicators cross linked by TEOS and cellulose acetate. Sensors (Basel) 18:3195
El-Nahhal IM, Zourab SM, Kodeh FS (2015) Entrapment of phenol red (PR) pH indicator into sol–gel matrix in presence of some surfactants. J Sol-Gel Sci Technol 75:313–322
Rabinovich YM, Kanicky RJ, Pandey S, Oskarsson H, Holmberge K, Moudgil BM, Shah DO (2005) Self-assembled Gemini surfactant film-mediated dispersion stability. J Colloid Interface Sci 288:583–590
Zaggout FR, El-Nahhal IM, Qaraman AE, Al Dahoudi N (2006) Behavior of thymol blue analytical pH-indicator entrapped into sol–gel matrix. Mater Lett 60:3463–3467
Lin Jie, Liu Dong (2000) An optical pH sensor with a linear response over a broad range. Anal Chim Acta 408:49–55
Capel-Cuevasa S, Cuéllarb MP, Orbe-Payáa I, Pegalajarb MC, Capitán-Vallvey LF (2011) Full-range optical pH sensor array based on neural networks. Microchem J 97:225–233
Afsaneh S, Norouz M, Mozhgan B (2007) Modification of chemical performance of dopants in xerogel films with entrapped ionic liquid. J Mater Chem 17:1633–1732
Jurmanović S, Kordić Š, Steinberg M, Steinberg IM (2010) Organically modified silicate thin films doped with colourimetric pH indicators methyl red and bromocresol green as pH responsive sol–gel hybrid materials. Thin Solid Films 518:2234–2240
Sanchez-Barragan I, Costa-Fernandez JM, Sanz-Mede A (2005) Tailoring the pH response range of fluorescent-based pH sensing phases by sol–gel surfactants co-immobilization. Sens Actuators B 107:69–76
Zhang Jianxin, Zhou Lei (2018) Preparation and optimization of optical pH sensor based on sol–gel. Sensors 18:3195
El Nahhal I, Zourab S, Kodeh F, Babonneau F, Hegazy W (2012) Sol–gel encapsulation of cresol red in presence of surfactants. J Sol-Gel Sci Technol 62:117–125
Acknowledgements
The authors would like to thank the Chemistry Department at Al-Azhar University of Gaza for its generous support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kodeh, F.S., El-Nahhal, I.M. & Abd el-salam, F.H. Sol–Gel Encapsulation of Thymol Blue in Presence of Some Surfactants. Chemistry Africa 2, 67–76 (2019). https://doi.org/10.1007/s42250-018-00039-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42250-018-00039-6