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An Ionic Liquid Immobilized Palladium Complex for an Effective Heck and Suzuki Coupling Reactions

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Abstract

A highly efficient catalytic activity towards Heck and Suzuki cross-coupling reactions was observed for a palladium complex in ethyl-methyl imidazolium hexafluorophosphate, [EMIM] PF6 ionic liquid medium, at ambient temperature. The system provides a stable, reusable method for the reaction. The optimization for the suitable reactions conditions was explored, and the effect of substituents on boronic acid was investigated. Using a very modest amount of catalyst, good-to-excellent yields were achieved. The reaction conditions were mild and most importantly, the catalyst-ionic liquid mixture was easily recoverable and reused for six times without much loss in the catalytic activity, causing negligible impact on the environment.

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Scheme 1
Fig. 1

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Acknowledgements

DR would like to thank the IISc Bangalore for all the spectroscopic analyses.

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Authors and Affiliations

  1. Department of Chemistry, School of Engineering, Presidency University, Yelahanka, Bangalore, 560064, India

    Dileep Ramakrishna

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  1. Dileep Ramakrishna
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Correspondence to Dileep Ramakrishna.

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Ramakrishna, D. An Ionic Liquid Immobilized Palladium Complex for an Effective Heck and Suzuki Coupling Reactions. Chemistry Africa 2, 21–28 (2019). https://doi.org/10.1007/s42250-018-00038-7

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  • DOI: https://doi.org/10.1007/s42250-018-00038-7

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