Upgrading and Refining of Crude Oils and Petroleum Products by Ionizing Irradiation

  • Yuriy A. Zaikin
  • Raissa F. Zaikina
Part of the following topical collections:
  1. Applications of Radiation Chemistry


A general trend in the oil industry is a decrease in the proven reserves of light crude oils so that any increase in future oil exploration is associated with high-viscous sulfuric oils and bitumen. Although the world reserves of heavy oil are much greater than those of sweet light oils, their exploration at present is less than 12 % of the total oil recovery. One of the main constraints is very high expenses for the existing technologies of heavy oil recovery, upgrading, transportation, and refining. Heavy oil processing by conventional methods is difficult and requires high power inputs and capital investments. Effective and economic processing of high viscous oil and oil residues needs not only improvements of the existing methods, such as thermal, catalytic and hydro-cracking, but the development of new technological approaches for upgrading and refining of any type of problem oil feedstock. One of the perspective approaches to this problem is the application of ionizing irradiation for high-viscous oil processing. Radiation methods for upgrading and refining high-viscous crude oils and petroleum products in a wide temperature range, oil desulfurization, radiation technology for refining used oil products, and a perspective method for gasoline radiation isomerization are discussed in this paper. The advantages of radiation technology are simple configuration of radiation facilities, low capital and operational costs, processing at lowered temperatures and nearly atmospheric pressure without the use of any catalysts, high production rates, relatively low energy consumption, and flexibility to the type of oil feedstock.


High-viscous oils Radiation-thermal cracking Low-temperature radiation cracking Used oil products Desulfurization Polymerization Isomerization 


  1. 1.
    Topchiev AV, Polak LS (1962) Radiolysis of hydrocarbons. Acad Sci USSR, MoscowGoogle Scholar
  2. 2.
    Topchiev AV (1964) Radiolysis of hydrocarbons. El Publ Co., Amsterdam, LondonGoogle Scholar
  3. 3.
    Brodskiy AM, Lavrovskiy KP, Zvonov NV, Titov VB (1961) Radiation-thermal conversion of oil fractions. Neftekhimiya (Oil Chemistry) 3:370–383Google Scholar
  4. 4.
    Lavrovsky KP (1976) Catalytic, thermal, and radiation-chemical conversion in hydrocarbons. Nauka Publ., Moscow, pp 312–373, 255–263Google Scholar
  5. 5.
    Gabsatararova SA, Kabakchi AM (1969) Effect of gamma-irradiation dose rate on formation of unsaturated compounds during radiation-thermal cracking of n-heptane. Khimiya Vysokikh Energiy (High Energy Chem) 3:126–128Google Scholar
  6. 6.
    Panchenkov GM, Putilov AV, Zhuravlev GI (1981) Study of basic regularities of n-decane radiation-thermal cracking. Khimiya Vysokikh Energiy (High Energy Chem) 15:426–430Google Scholar
  7. 7.
    Zaikina RF, Zaikin YA, Mirkin G, Nadirov NK (2002) Prospects of radiation technology application in oil industry. Radiat Phys Chem 63:621–624CrossRefGoogle Scholar
  8. 8.
    Mirkin G, Zaikin YA, Zaikina RF (2003) Radiation methods for upgrading and refining of feedstock for oil chemistry. Radiat Phys Chem 67:311–314CrossRefGoogle Scholar
  9. 9.
    Nadirov NK, Zaikina RF, Zaikin YuA (1994) Progress in high viscosity oil and natural bitumen refining by ionizing irradiation. Oil Bitumen Kazan 4:1638–1642Google Scholar
  10. 10.
    Nadirov NK, Zaikina RF, Zaikin YA (1995) New high-efficient technologies for heavy oil and oil residue refining. Energy Fuel Resour Kazakhstan 1:65–69Google Scholar
  11. 11.
    Zaikin YA, Zaykina RF, Mamonova TB, Nadirov NK (2001) Radiation-thermal processing of high-viscous oil from Karazhanbas field. Radiat Phys Chem 60:211–221CrossRefGoogle Scholar
  12. 12.
    Zaikina RF, Zaikin YA, Mamonova TB (2002) Radiation methods for demercaptanization and desulfurization of oil products. Radiat Phys Chem 63:617–619CrossRefGoogle Scholar
  13. 13.
    Zaikina RF, Zaikin YA (2003) Radiation technologies for production and regeneration of motor fuels and lubricants. Radiat Phys Chem 65:169–172CrossRefGoogle Scholar
  14. 14.
    Zaikin YA, Zaikina RF, Silverman J (2004) Radiation-thermal conversion of paraffinic oil. Radiat Phys Chem 69:229–238CrossRefGoogle Scholar
  15. 15.
    Zaikina RF, Zaikin YA, Yagudin ShG, Fahruddinov IM (2004) Specific approaches to radiation processing of high-sulfuric oil. Radiat Phys Chem 71:467–470CrossRefGoogle Scholar
  16. 16.
    Zaikin YA, Zaikina RF (2004) Bitumen radiation processing. Radiat Phys Chem 71:471–474CrossRefGoogle Scholar
  17. 17.
    Zaikin YA, Zaikina RF (2007) Effect of radiation-induced isomerization on gasoline upgrading. In: Proceedings of the 8th topical meeting on nuclear applications and utilization of accelerators AccApp’07, Pocatello, Idaho, July 29-August 2, 2007. American Nuclear Society, pp 993–998Google Scholar
  18. 18.
    Zaikin YA (2013) On the nature of radiation-excited unstable states of hydrocarbon molecules in heavy oil and bitumen. Radiat Phys Chem 84:6–9CrossRefGoogle Scholar
  19. 19.
    Zaikin Y, Zaikina R (2013) Petroleum radiation processing. Taylor & Francis, CRC, New York, Boca RatonCrossRefGoogle Scholar
  20. 20.
    Zaikin YA, Zaikina RF, Nadirov NK (2014) The phenomenon of the radiation-enhanced isomerization of hydrocarbon systems. In: International academy of the authors of scientific discoveries and inventions. Certificate of discovery A-589 of Nov 4, 2013; Diploma #463. The year of priority: 2001Google Scholar
  21. 21.
    Zaikin Y, Zaikina R (2008) PetroBeam process for heavy oil upgrading. World Heavy Oil Conference, Edmonton 10–12 March, 2008, WHOC, paper 2008-461Google Scholar
  22. 22.
    Zaikin YA (2008) Low-temperature radiation-induced cracking of liquid hydrocarbons. Radiat Phys Chem 77:1069–1073CrossRefGoogle Scholar
  23. 23.
    ZaikinY A (2013) Radiation-induced cracking of hydrocarbons. In: Kharissov BI, Kharissova OV, Mendez UO (eds) Radiation synthesis of materials and compounds. Taylor & Francis, CRC, New York, Boca Raton, pp 355–379Google Scholar
  24. 24.
    Zaikin YA, Zaikina RF (2008) New trends in the radiation processing of petroleum. In: Camillery AN (ed) Radiation physics research progress. Nova Science, New York, pp 17–103Google Scholar
  25. 25.
    Zaikin YA, Zaikina RF (2012) Self-sustaining cold cracking of hydrocarbons. US patents 8,192, 591 and 8,911,617; Eurasian patent 016698, Patent of Canada 2633885, Patent of China 200680051814.1, Patent of Mexico 309717, Patent of India 259292Google Scholar
  26. 26.
    Bugaenko LP, Kuzmin MG, Polak LS (1988) Chemistry of high energy. Chimiya, MoscowGoogle Scholar
  27. 27.
    Zaikin YA (2013) Polymerization as a limiting factor for light product yields in radiation cracking of heavy oil and bitumen. Radiat Phys Chem 84:2–5CrossRefGoogle Scholar
  28. 28.
    Zaikin YA, Zaikina RF, Mirkin G (2003) On energetics of hydrocarbon chemical reactions by ionizing irradiation. Radiat Phys Chem 67(3–4):305–309CrossRefGoogle Scholar
  29. 29.
    Nadirov NK, Zaikin YA, Zaikina RF, Makulbekov EA, Petukhov VK, Panin YA (1994) Method for processing heavy oil and oil residua. Patent of Kazakhstan 4676Google Scholar
  30. 30.
    Zaikin YA et al (2006) Experimental facility for processing hydrocarbon components of natural bitumen. Almaty, Technical report on ISTC project K-930Google Scholar
  31. 31.
    Akpabio EJ (1992) Cand. Diss. Thesis. BakuGoogle Scholar
  32. 32.
    Musaev GF, Mamonova TB, Malibov MS, Musaeva ZG (1994) Study of Kazakhstani bitumen rocks by the thermocatalytic method. Energy Fuel Resour Kazakhstan 4:51–56Google Scholar
  33. 33.
    Zaikin YA, Zaikina RF, Nadirov NK, Sarsembinov ShSh (1999) Method and apparatus for reprocessing of used and residual mixtures of oil products. Patent of Kazakhstan 8142Google Scholar
  34. 34.
    Zaikin YA (2005) New technological approaches to cleaning, upgrading and desulfurization of oil wastes and low-grade oil products. In: Proceedings of the 4th international conference “Oils and Environment”. Gdansk University of Technology, pp 275–282Google Scholar
  35. 35.
    Ivanov VS (1988) Radiation chemistry of polymers. Khimiya, Leningrad, pp 299–300Google Scholar
  36. 36.
    Chmielewski AG (2011) Electron accelerators for environmental protection. Rev Accel Sci Technol 4:149–161CrossRefGoogle Scholar
  37. 37.
    Pawelec A et al (2016) Fuel Process Technol 145:123–129CrossRefGoogle Scholar
  38. 38.
    Zaikina RF, Zaikin YA, Mamonova TB, Nadirov NK (1999) A method for hydrocarbon feedstock cleaning with the removal of sulfur compounds. Patent of Kazakhstan 11995Google Scholar
  39. 39.
    Likhterova NM, Lunin VV, Kukulin VI, Knipovich OM, Torkhovskiy VN (1998) A method for petroleum feedstock processing. Patent of Russia RU 212040Google Scholar
  40. 40.
    Lunin VV, Frantsuzov VK, Likhterova NM (2012) Desulfurization and demetallization of heavy oil fractions by ozonolysis and radiolysis. Neftekhimiya (Petrol Chem) 42(36):195–202Google Scholar
  41. 41.
    Ayukawa Y, Ono M (2004) High-energy beam irradiating desulfurization device. US Patent 6,284,746B2Google Scholar
  42. 42.
    Basfar AA, Khaled A-AM (2012) Method of removing sulfur from crude oil by ionizing irradiation. Pub/No. US 2012/0138449 A1Google Scholar
  43. 43.
    Qu Z, Yan N, Jia J, Wu D (2006) Removal of thiophene-type sulfide by gamma radiation assisted with hydrogen peroxide. Energy Fuels 20:142–147CrossRefGoogle Scholar
  44. 44.
    Tian Y, Yan N, Li D, Yao S, Wang W (2003) Removal of dibenzothiophene from simulated petroleum by integrated γ-irradiation and Zr/alumina catalyst. J Chem Ind Eng (China) 54:1279–1283Google Scholar
  45. 45.
    Zhao YF, Yan NG, Wu D, Jia JP, Qu Z (2004) Investigation on removal of thiophene-type sulfide by gamma rays radiation assisted with hydrogen peroxide. J Shanghai Jiatong Univ 38:1719–1723Google Scholar
  46. 46.
    Chandrasekhar S (1947) Stochastic problems in physics and astronomy. Inostrannaya Literatura, MoscowGoogle Scholar
  47. 47.
    Chmielewski AG, Haji-Saeid M (2004) Radiation technologies: past, present and future. Radiat Phys Chem 71:17–21CrossRefGoogle Scholar
  48. 48.
    Haji-Saeid M et al (2007) Nuclear instruments and methods in physics research. Sect B Beam Interact Mater Atoms 265:51–57Google Scholar
  49. 49.
    Zaikin YA, Zaikina RF (2004) Criteria of synergetic effects in radiation-induced conversion of complex hydrocarbon mixtures. Oil Gas (Kazakhstan) 22(2):64–73Google Scholar
  50. 50.
    Allara DL (1980) A compilation of kinetic parameters for the thermal degradation of n-alkane molecules. J Phys Chem Ref Data 9(3):523–525CrossRefGoogle Scholar
  51. 51.
    Talrose VL (1974) To the theory of radiation-chemical initiation of chain reactions. Khimiya Vysokikh Energiy (High-Energy Chem) 8:519–527Google Scholar

Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  1. 1.PetroBeam, Inc.SweetwaterUSA

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