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Materials Integrating Photochemical Upconversion

  • Catherine E. McCusker
  • Felix N. Castellano
Review
Part of the following topical collections:
  1. Photoluminescent Materials and Electroluminescent Devices

Abstract

This review features recent experimental work focused on the preparation and characterization of materials that integrate photochemical upconversion derived from sensitized triplet–triplet annihilation, resulting in the conversion of low energy photons to higher energy light, thereby enabling numerous wavelength-shifting applications. Recent topical developments in upconversion include encapsulating or rigidifying fluid solutions to give them mechanical strength, adapting inert host materials to enable upconversion, and using photoactive materials that incorporate the sensitizer and/or the acceptor. The driving force behind translating photochemical upconversion from solution into hard and soft materials is the incorporation of upconversion into devices and other applications. At present, some of the most promising applications of upconversion materials include imaging and fluorescence microscopy, photoelectrochemical devices, water disinfection, and solar cell enhancement.

Keywords

Photochemical upconversion Triplet–triplet Annihilation Wavelength shifting Light emitting materials Solid state upconversion Soft photonic materials 

Notes

Acknowledgments

This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Award Number DE-SC0011979. Some of the work on solid-state upconversion performed in this laboratory was supported by the Air Force Office of Scientific Research (FA9550-13-1-0106).

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Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  1. 1.Department of ChemistryNorth Carolina State UniversityRaleighUSA

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