Skip to main content
Log in

Effects of Al–Ti–C–Ce Master Alloy on Microstructure and Mechanical Properties of Hypoeutectic Al–7%Si Alloy

  • Published:
International Journal of Metalcasting Aims and scope Submit manuscript

Abstract

It is well known that the mechanical properties of hypoeutectic Al–7%Si alloys are influenced by the size, morphology, and distribution of primary α-Al and eutectic Si crystals. In the present work, a novel Al–TiCCe master alloy was prepared by the pure molten aluminum thermal explosion reaction, and its effects on the microstructure and mechanical properties of hypoeutectic Al–7%Si alloy were investigated. The results show that the Al–TiCCe master alloy containing α-Al, granular TiC, lump-like TiAl3, and block-like Ti2Al20Ce has excellent refining and modification properties for hypoeutectic Al–7%Si alloy. When 1.5 wt.% Al–TiCCe master alloy is added, the coarse dendritic α-Al in hypoeutectic Al–7%Si alloy is refined into equiaxed grains. The secondary dendritic arm spacing (SDAS) was also reduced, and the coarse needle-flake eutectic Si phase was transformed into a fibrous and granular phase. It was found that the ultimate tensile strength and elongation increased by 59% and 56%, respectively, due to the decrease in the SDAS of primary α-Al dendrites and the modification of eutectic Si crystals. Moreover, the change of mechanical properties corresponds to the evolution of microstructure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12

Similar content being viewed by others

References

  1. J. Rakhmonov, G. Timelli, F. Bonollo, L. Arnberg, Influence of grain refiner addition on the precipitation of Fe-rich phases in secondary AlSi7Cu3Mg alloys. Int. J. Metalcast. 11, 294–304 (2017)

    Article  Google Scholar 

  2. D.G. Mallapur, K. Rajendra Udupa, S.A. Kori, Studies on the influence of grain refining and modification on microstructure and mechanical properties of forged A356 alloy. Mater. Sci. Eng. A 528, 4747–4752 (2011)

    Article  Google Scholar 

  3. S.L. Lee, Y.C. Cheng, W.C. Chen, C.K. Lee, A.H. Tan, Effects of strontium and heat treatment on the wear-corrosion property of Al–7Si–0.3Mg alloy. Mater. Chem. Phys. 135, 503–509 (2012)

    Article  Google Scholar 

  4. Q.L. Li, F.B. Li, T.D. Xia, Y.F. Lan, Y.S. Jian, F. Tao, Effects of in situ γ-Al2O3 particles and heat treatment on the microstructure and mechanical properties of A356 aluminium alloy. J. Alloys Compd. 627, 352–358 (2015)

    Article  Google Scholar 

  5. G.K. Sigworth, Understanding quality in aluminum castings. Int. J. Metalcast. 5, 7–22 (2011)

    Article  Google Scholar 

  6. G.K. Sigworth, Fundamentals of solidification in aluminum castings. Int. J. Metalcast. 8, 7–20 (2014)

    Article  Google Scholar 

  7. J.H. Li, M.Z. Zarif, M. Albu, B.J. McKay, F. Hofer, P. Schumacher, Nucleation kinetics of entrained eutectic Si in Al-5Si alloys. Acta Mater. 72, 80–98 (2014)

    Article  Google Scholar 

  8. K.G. Basavakumar, P.G. Mukunda, M. Chakraborty, Influence of grain refinement and modification on microstructure and mechanical properties of Al-7Si and Al-7Si-2.5Cu cast alloys. Mater. Charact. 59, 283–289 (2008)

    Article  Google Scholar 

  9. G.K. Sigworth, The modification of Al-Si casting alloys: important practical and theoretical aspects. Int. J. Metalcast. 2, 19–40 (2008)

    Article  Google Scholar 

  10. S.D. McDonald, K. Nogita, A.K. Dahle, Eutectic nucleation in Al-Si alloys. Acta Mater. 52, 4273–4280 (2004)

    Article  Google Scholar 

  11. A.K. Dahle, K. Nogita, S.D. McDonald, C. Dinnis, L. Lu, Eutectic modification and microstructure development in Al-Si Alloys. Mater. Sci. Eng. A 413–414, 243–248 (2005)

    Article  Google Scholar 

  12. O. Uzun, F. Yılmaz, U. Ko¨lemen, N. Basman, Sb effect on micro structural and mechanical properties of rapidly solidified Al-12Si alloy. J. Alloys Compd. 509, 21–26 (2011)

    Article  Google Scholar 

  13. C.X. Xu, L.P. Liang, B.F. Lu, J.S. Zhang, L. Wei, Effect of La on microstructure and grain–refining performance of Al-Ti-C grain refiner. J. Rare Earths 24, 596–601 (2006)

    Article  Google Scholar 

  14. T. Lu, Y. Pan, J.L. Wu, S.W. Shi, Y. Chen, Effects of La addition on the microstructure and tensile properties of Al-Si-Cu-Mg casting alloys. Int. J. Miner. Metal. Mater. 22, 405–410 (2015)

    Article  Google Scholar 

  15. M.G. Mahmoud, E.M. Elgallad, M.F. Ibrahim, F.H. Samuel, Effect of rare earth metals on porosity formation in A356 alloy. Int. J. Metalcast. 12, 251–265 (2018)

    Article  Google Scholar 

  16. D. Yao, F. Qiu, Q. Jiang, Y. Li, L. Arnberg, Effect of lanthanum on grain refinement of casting aluminum-copper alloy. Int. J. Metalcast. 7, 49–54 (2013)

    Article  Google Scholar 

  17. B. Li, H.W. Wang, J.C. Jie, Z.J. Wei, Microstructure evolution and modification mechanism of the ytterbium modified Al-7.5%Si-0.45%Mg alloys. J. Alloys Compd. 509, 3387–3392 (2011)

    Article  Google Scholar 

  18. Q.L. Li, T.D. Xia, Y.F. Lan, W.J. Zhao, L. Fan, P.F. Li, Effect of rare earth cerium addition on the microstructure and tensile properties of hypereutectic Al-20%Si alloy. J. Alloys Compd. 562, 25–32 (2013)

    Article  Google Scholar 

  19. X.F. Liu, Z.Q. Wang, Z.G. Zhang, The relationship between microstructures and refining performances of Al-Ti-C master alloys. Mater. Sci. Eng. A 332, 70–74 (2002)

    Article  Google Scholar 

  20. G.K. Sigworth, T.A. Kuhn, Grain refinement of aluminum casting alloys. Int. J. Metalcast. 1, 31–40 (2007)

    Article  Google Scholar 

  21. Y.L. Li, H.K. Feng, F.R. Cao, Y.B. Chen, L.Y. Gong, Effect of high density ultrasonic on the microstructure and refining property of Al–5Ti–0.25C grain refiner alloy. Mater. Sci. Eng. A 487, 518–523 (2008)

    Article  Google Scholar 

  22. G.S. Kumar, B.S. Murty, M. Chakraborty, Development of Al–Ti–C grain refiners and study of their grain refining efficiency on Al and Al–7Si alloy. J. Alloys Compd. 396, 143–150 (2005)

    Article  Google Scholar 

  23. V.H. López, A. Scoles, A.R. Kennedy, The thermal stability of TiC particles in an Al-7wt.%Si alloy. Mater. Sci. Eng. A 356, 316–325 (2003)

    Article  Google Scholar 

  24. J.H. Wu, H.L. Zhao, J.X. Zhou, W.H. Li, J.W. Wang, L.L. Zhang, Effects of Al-Ti-B-Sr master alloy on the microstructure and mechanical properties of A356 alloy. Mater. Sci. Forum 898, 131–136 (2017)

    Article  Google Scholar 

  25. A.K. Prasada Rao, K. Das, B.S. Murty, M. Chakraborty. Microstructures and wear behavior of hypoeutectic Al-Si alloy (LM25) grain refined and modified with Al-Ti-C-Sr master alloy. Wear 261, 133–139 (2006)

    Article  Google Scholar 

  26. H.L. Zhao, J.S. Yue, Y. Gao, K.R. Weng, Grain and dendrite refinement of A356 alloy with Al-Ti-C-RE master alloy. Rare Met. 32, 12–17 (2013)

    Article  Google Scholar 

  27. C. Xu, W.L. Xiao, W.T. Zhao, W.H. Wang, H. Shuji, Y. Hiroshi, C.L. Ma, Microstructure and formation mechanism of grain-refining particles in Al-Ti-C-RE grain refiners. J. Rare Earths 33, 553–560 (2015)

    Article  Google Scholar 

  28. L. Lu, A.K. Dahle, Effect of combined additions of Sr and Al-Ti-B grain refiners in hypoeutectic Al-Si foundry alloys. Mater. Sci. Eng. A 435–436, 288–296 (2006)

    Article  Google Scholar 

  29. X.G. Qi, X.F. Bian, Y.H. Wang, Grain refinement and modification effects of Al-Ti-B and Al-5%Sr master alloys on the wheel aluminum alloy. Foundry 49, 321–326 (2000)

    Google Scholar 

  30. Y.M. Liu, B.F. Xu, X. Cai, L.H. Li, Q.L. Chen, The preparation of in situ TiC/Al composite by additive CeO2. J. Shanghai Jiaotong Univ. 38, 1122–1125 (2004)

    Google Scholar 

  31. Q.L. Wu, Y.S. Sun, F. Xue, J. Zhuo, Effect of CeO2 addition on microstructure and properties of in situ TiC strengthened steel. J. Chin. Rare Earth Soc. 26, 92–96 (2008)

    Google Scholar 

  32. L.D. Wang, Z.L. Wei, X.B. Yang, D.Y. Zhu, X. Chen, Y.L. Chen, L.H. Hong, Q.J. Li, Thermodynamic analysis of Al-Ti-C-RE prepared by rare Earth oxide Ce2O3. Trans. Nonferr. Met. Soc. China 23, 2928–2935 (2013)

    Google Scholar 

  33. W.W. Ding, C. Xu, H.X. Zhang, W.J. Zhao, T.B. Guo, T.D. Xia, Effect of Al-5Ti-0.62C-0.2Ce master alloy on the microstructure and tensile properties of commercial pure Al and hypoeutectic Al-8Si alloy. Metals 7, 227–240 (2017)

    Article  Google Scholar 

  34. W.W. Ding, X.Y. Zhang, W.J. Zhao, T.D. Xia, Microstructure of Al-5Ti-0.6C-1Ce master alloy and its grain-refining performance. Int. J. Mater. Res. 106, 1240–1243 (2015)

    Article  Google Scholar 

  35. Q. Ma, Heterogeneous nucleation on potent spherical substrates during solidification. Acta Mater. 55, 943–953 (2007)

    Article  Google Scholar 

  36. A.L. Greer, A.M. Bunn, A. Tronche, P.V. Evans, D.J. Bristow, Modelling of inoculation of metallic melts: application to grain refinement of aluminium by Al-Ti-B. Acta Mater. 48, 2823–2835 (2000)

    Article  Google Scholar 

  37. C. Small, P. Prangnell, F. Hayes, A. Hardman, Microstructure and grain refining efficiency of TiC particles in Al-Ti-C grain refining master alloys, in ICAA-6: 6th International Conference on Aluminium Alloys, Toyohashi, Japan (1998), p. 213

  38. A. Banerji, W. Reif, Development of Al-Ti-C grain refiners containing TiC. Metall. Trans. A 17, 2127–2137 (1986)

    Article  Google Scholar 

  39. T.D. Xia, W.W. Ding, W.J. Zhao, Effect of distribution of TiC in aluminum matrix in the presence of solute TiAl3 and nucleation mechanism of Al-Ti-C. Trans. Nonferr. Met. Soc. China 19, 1948–1955 (2009)

    Google Scholar 

  40. W.W. Ding, W.J. Zhao, T.D. Xia, Grain refining action of Al-5Ti-C and Al-TiC master alloys with Al-5Ti master alloy addition for commercial purity aluminum. Int. J. Cast. Metal. Res. 27, 187–192 (2014)

    Article  Google Scholar 

  41. S.H. Wang, Z.F. Wang, X.Y. Fan, X.F. Jia, Y. Zhao, L. Zhang, Effect of different RE Ce master alloy on microstructure of A356 alloy. China Foundry Mach. Technol. 4, 7–11 (2010)

    Google Scholar 

  42. G.K. Sigworth, M.M. Guzowaski, Grain refining of hypo-eutectic Al-Si alloys. AFS Trans. 93, 907–912 (1985)

    Google Scholar 

  43. D. Qiu, J.A. Taylor, M.X. Zhang, P.M. Kelly, A mechanism for the poisoning effect of silicon on the grain refinement of Al-Si alloys. Acta Mater. 55, 1447–1456 (2007)

    Article  Google Scholar 

  44. P.T. Li, S.D. Liu, L.L. Zhang, X.F. Liu, Grain refinement of A356 alloy by Al-Ti-B-C master alloy and its effect on mechanical properties. Mater. Design. 47, 522–528 (2013)

    Article  Google Scholar 

  45. Q.L. Li, B.Q. Li, J.B. Li, T.D. Xia, Y.F. Lan, T.B. Guo, Effects of the addition of Mg on the microstructure and mechanical properties of hypoeutectic Al-7%Si alloy. Int. J. Metalcast. 11, 823–830 (2017)

    Article  Google Scholar 

  46. X.S. Li, A.H. Cai, Y. Luo, Influence of B refinement on mechanical properties and fracture surfaces of hypoeutectic Al–Si alloy. J. Hunan Inst. Sci. Technol. 22, 34–38 (2009)

    Google Scholar 

Download references

Acknowledgements

We would like to thank LetPub (www.letpub.com) for providing linguistic assistance during the preparation of this manuscript. This research was financially supported by the National Natural Science Foundation of China (Nos. 51661021; 51665033). The authors would like to acknowledge the financial support of the Natural Science Foundation of Gansu Province in China (No. 1606RJZA161) and Gansu key research and development program (No. 18YF1GA061).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Wanwu Ding.

Ethics declarations

Conflict of interest

The authors declare no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ding, W., Zhao, X., Zhao, W. et al. Effects of Al–Ti–C–Ce Master Alloy on Microstructure and Mechanical Properties of Hypoeutectic Al–7%Si Alloy. Inter Metalcast 13, 426–437 (2019). https://doi.org/10.1007/s40962-018-0266-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40962-018-0266-8

Keywords

Navigation