Science China Materials

, Volume 62, Issue 5, pp 751–758 | Cite as

Cationic and anionic energetic materials based on a new amphotère

  • Yuangang Xu (许元刚)
  • Pengcheng Wang (王鹏程)
  • Qiuhan Lin (林秋汉)
  • Yao Du (杜耀)
  • Ming Lu (陆明)Email author



本文报道了5,5ʹ-二氨基-4,4ʹ-二硝氨基-3,3ʹ-双-1,2,4-三唑(1)的第一种阳离子形式及其合成和表征. 化合物1与硝酸反应生成了5, 与RDX相比, 这是一种具有更高的分解温度和更好爆轰性能的炸药, 与HMX相比其感度更低. 1的阴离子作为配体和钾离子的自组装合成了起爆药4, 与目前广泛使用的Pb(N3)2相比较, 它的性能更加优异. 两性化合物1的两个衍生物的分离具有重要意义: (1) 说明了化合物1的两 性性质; (2) 开启了它们作为有前景的含能前体的研究, 为更多含能离子盐的合成提供参考.



This work was financially supported by the joint fund of the National Natural Science Foundation of China and China Academy of Engineering Physics (NSAF, U1530101). We also thank Zaiyong Zhang (Shanghai Institute of Materia Medica) for the analysis of the crystal structures.

Supplementary material

40843_2018_9374_MOESM1_ESM.pdf (611 kb)
Cationic and anionic energetic materials based on a new amphotère


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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Yuangang Xu (许元刚)
    • 1
  • Pengcheng Wang (王鹏程)
    • 1
  • Qiuhan Lin (林秋汉)
    • 1
  • Yao Du (杜耀)
    • 2
  • Ming Lu (陆明)
    • 1
    Email author
  1. 1.School of Chemical EngineeringNanjing University of Science and TechnologyNanjingChina
  2. 2.School of Materials Science & EngineeringBeijing Institute of TechnologyBeijingChina

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