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Biofuel Impact on Diesel Engine After-Treatment: Deactivation Mechanisms and Soot Reactivity

  • Special Article from the ETH conference 2017
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Abstract

Since 2014 (Euro VI), heavy goods vehicles must be equipped with a complex exhaust gas post-treatment system including a diesel oxidation catalyst (DOC), a catalyst for the selective reduction of NOx (SCR), and a diesel particulate filter (DPF), with a required durability of 7 years or 700,000 km. Consequently, when biodiesel is used, especially pure biodiesel (B100), catalysts will be subjected over 700,000 km to kilogrammes of inorganic elements (Na, K, and P), even if they are limited to a few ppm in biodiesel fuel. The durability of the catalytic exhaust system is therefore questionable. This issue is of major concern to vehicle manufacturers. This study aims to make a detailed investigation of the impact of biodiesel use on the durability of the existing Euro VI catalytic systems, with a special focus on deactivation through poisoning for DOC and SCR catalysts, and on the physics and chemistry of particles and their reactivity.

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Acknowledgements

The authors gratefully acknowledge the French National Agency (ANR) for Research for its financial support (Appibio Project, Ref. ANR-14-CE22-0003).

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Authors and Affiliations

  1. Renault Trucks-Volvo Group Trucks Technology, Powertrain Engineering, 99 route de Lyon, 69806, Saint-Priest Cedex, France

    E. Iojoiu & V. Lauga

  2. Sorbonne Universités, UPMC, Univ. Paris 6, CNRS, UMR 7190Institut Jean Le Rond d’Alembert (IJLRA), 2 place de la gare de ceinture, 78210, Saint-Cyr-L’Ecole, France

    J. Abboud, G. Legros, J. Bonnety & P. Da Costa

  3. Université de Haute Alsace, Laboratoire Gestion des Risques et Environnement (LGRE) EA2334, 3b rue A. Werner, Institut J.B. Donnet, 68093, Mulhouse Cedex, France

    J. Schobing, A. Brillard, G. Leyssens & V. Tschamber

  4. Université de Lyon, 69003, Lyon, France

    P. Anguita, J. G. Vargas, L. Retailleau, S. Gil & A. Giroir-Fendler

  5. Université Claude Bernard Lyon 1, Villeurbanne, 69622, Lyon, France

    P. Anguita, J. G. Vargas, L. Retailleau, S. Gil & A. Giroir-Fendler

  6. CNRS, UMR 5256, IRCELYON|, 2 avenue Albert Einstein, 69622, Villeurbanne, France

    P. Anguita, J. G. Vargas, L. Retailleau, S. Gil & A. Giroir-Fendler

  7. Institut de Chimie des Milieux et des Matériaux de Poitiers (IC2MP), Université de Poitiers-CNRS, UMR 7285, 4 rue Michel Brunet, TSA 51106, 86073, Poitiers Cedex 9, France

    M.-L. Tarot, F. Can, D. Duprez & X. Courtois

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  1. E. Iojoiu
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  2. V. Lauga
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  17. F. Can
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  18. D. Duprez
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Iojoiu, E., Lauga, V., Abboud, J. et al. Biofuel Impact on Diesel Engine After-Treatment: Deactivation Mechanisms and Soot Reactivity. Emiss. Control Sci. Technol. 4, 15–32 (2018). https://doi.org/10.1007/s40825-017-0079-x

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  • Issue Date:

  • DOI: https://doi.org/10.1007/s40825-017-0079-x

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