Abstract
All manufacturing sectors use cutting fluids. Need for sustainable manufacturing discourages the application of cutting fluid as flood and encourages their application in small quantity strictly at the cutting zone, i.e., minimum quantity lubrication (MQL). But, MQL application requires development of cutting fluids with augmented properties. Present work performs quantitative analysis of dispersion, cooling and lubricating properties of graphene dispersed emulsifier oil. In the present work, initially 0.1 wt% graphene dispersed emulsifier oil samples are prepared by using different surfactants, sonication times and graphene to surfactant ratios and optimal conditions are identified which showed maximum dispersion stability. Absorbance method is use to evaluate dispersion stability. Use of Triton X100 with graphene to surfactant ratio of 1.5 and sonication time of 60 s is found to be the optimum condition. Properties like density, kinematic viscosity and dynamic viscosity are evaluated and ratio of graphene to surfactant is decided for 0.3 wt% and 0.5 wt% graphene dispersed emulsifier oil. Thermal conductivity and tribological properties are evaluated to quantitatively analyze the cooling and lubricating properties of graphene dispersed emulsifier oil. Emulsifier oil with 0.1 wt%, 0.3 wt% and 0.5 wt% graphene with surfactant Triton X100 added in same ratio as graphene showed enhancement viscosity which is 1.6, 2.6 and 3.4 times the viscosity of base emulsifier oil and also showed good stability. The corresponding thermal conductivities are found to be 1.1, 2 and 1.5 times the thermal conductivity of base emulsifier oil and coefficient of friction is found to decrease by 0.6%, 2.9% and 5.8%, respectively. Good stability, enhanced viscosity, thermal conductivity and reduced coefficient of friction make them suitable for machining applications.
Similar content being viewed by others
References
https://www.meadmetals.com/blog/common-uses-for-stainless-steel
Leyens C, Peters M (eds) (2003) Titanium and titanium alloys: fundamentals and applications. Wiley, London
Reed RC (2008) The superalloys: fundamentals and applications. Cambridge University Press, Cambridge
Youssef HA (2015) Machining of stainless steels and superalloys: traditional and nontraditional techniques. Wiley, London
Ahmed YS, Paiva JM, Arif AFM, Amorim FL, Torres RD, Veldhuis SC (2020) The effect of laser micro-scale textured tools on the tool-chip interface performance and surface integrity during austenitic stainless-steel turning. Appl Surf Sci 510:145455
Manikandan N, Arulkirubakaran D, Palanisamy D, Raju R (2019) Influence of wire-EDM textured conventional tungsten carbide inserts in machining of aerospace materials (Ti–6Al–4V alloy). Mater Manuf Processes 34(1):103–111
Sivaiah P, Ajay Kumar GV, Singh MM, Kumar H (2020) Effect of novel hybrid texture tool on turning process performance in MQL machining of Inconel 718 superalloy. Mater Manuf Process 35(1):61–71
Deshpande YV, Andhare AB, Padole PM (2018) Experimental results on the performance of cryogenic treatment of tool and minimum quantity lubrication for machinability improvement in the turning of Inconel 718. J Braz Soc Mech Sci Eng 40(1):6
Saini A, Pabla BS, Dhami SS (2019) Improvement in performance of cryogenically treated tungsten carbide tools in face milling of Ti–6Al–4V alloy. Mater Manuf Process 35:1–10
Chaudhury MD, Subramanian A (2019). Metallurgical changes of cryogenically treated Coated Carbide (KC-9225) and its performance during wet machining of Austenitic Stainless Steel–310. In: IOP conference series: materials science and engineering, vol. 502, no. 1. IOP Publishing, p 012192
Ahmed YS, Paiva JM, Veldhuis SC (2019) Characterization and prediction of chip formation dynamics in machining austenitic stainless steel through supply of a high-pressure coolant. Int J Adv Manuf Technol 102(5–8):1671–1688
Khanna N, Agrawal C, Gupta MK, Song Q (2020) Tool wear and hole quality evaluation in cryogenic drilling of Inconel 718 superalloy. Tribol Int 143:106084
Dureja JS, Singh R, Singh T, Singh P, Dogra M, Bhatti MS (2015) Performance evaluation of coated carbide tool in machining of stainless steel (AISI 202) under minimum quantity lubrication (MQL). Int J Precis Eng Manuf Green Technol 2(2):123–129
Kamata Y, Obikawa T (2007) High speed MQL finish-turning of Inconel 718 with different coated tools. J Mater Process Technol 192:281–286
Sadeghi MH, Haddad MJ, Tawakoli T, Emami M (2009) Minimal quantity lubrication-MQL in grinding of Ti–6Al–4V titanium alloy. Int J Adv Manuf Technol 44(5–6):487–500
Berk Z (2018) Food process engineering and technology. Academic Press, London
Das SK, Choi SU, Yu W, Pradeep T (2007) Nanofluids: science and technology. Wiley, London
Uysal A, Demiren F, Altan E (2015) Applying minimum quantity lubrication (MQL) method on milling of martensitic stainless steel by using nano MoS2 reinforced vegetable cutting fluid. Proced Soc Behav Sci 195:2742–2747
Sodavadia KP, Makwana AH (2014) Experimental investigation on the performance of coconut oil based nano fluid as lubricants during turning of AISI 304 austenitic stainless steel. Int J Adv Mech Eng 4(1):55–60
Sahu NK, Andhare AB, Raju RA (2018) Evaluation of performance of nanofluid using multiwalled carbon nanotubes for machining of Ti–6AL–4V. Mach Sci Technol 22(3):476–492
Setti D, Ghosh S, Paruchuri VR (2018) Influence of nanofluid application on wheel wear, coefficient of friction and redeposition phenomenon in surface grinding of Ti-6Al-4V. Proc Inst Mech Eng Part B J Eng Manuf 232(1):128–140
Sinha MK, Madarkar R, Ghosh S, Rao PV (2017) Application of eco-friendly nanofluids during grinding of Inconel 718 through small quantity lubrication. J Clean Prod 141:1359–1375
Hegab H, Kishawy HA (2018) Machining of Inconel 718 using nano-fluid minimum quantity lubrication. In: 7th International conference on virtual machining process technology (VMPT)
Bai X, Li C, Dong L et al (2019) Experimental evaluation of the lubrication performances of different nanofluids for minimum quantity lubrication (MQL) in milling Ti–6Al–4V. Int J Adv Manuf Technol 101:2621–2632. https://doi.org/10.1007/s00170-018-3100-9
Amrita M, Srikant RR, Sitaramaraju AV, Prasad MMS, Krishna PV (2014) Preparation and characterization of properties of nanographite-based cutting fluid for machining operations. Proc Inst Mech Eng Part J J Eng Tribol 228(3):243–252
Pop E, Varshney V, Roy AK (2012) Thermal properties of graphene: fundamentals and applications. MRS Bull 37(12):1273–1281
Berman D, Erdemir A, Sumant AV (2014) Graphene: a new emerging lubricant. Mater Today 17(1):31–42
Li M, Yu T, Yang L, Li H, Zhang R, Wang W (2019) Parameter optimization during minimum quantity lubrication milling of TC4 alloy with graphene-dispersed vegetable-oil-based cutting fluid. J Clean Prod 209:1508–1522
Li M, Yu T, Zhang R, Yang L, Ma Z, Li B, Zhao J (2020) Experimental evaluation of an eco-friendly grinding process combining minimum quantity lubrication and graphene-enhanced plant-oil-based cutting fluid. J Clean Prod 244:118747
De Oliveira D, Da Silva RB, Gelamo RV (2019) Influence of multilayer graphene platelet concentration dispersed in semi-synthetic oil on the grinding performance of Inconel 718 alloy under various machining conditions. Wear 426:1371–1383
Li G, Yi S, Li N, Pan W, Wen C, Ding S (2019) Quantitative analysis of cooling and lubricating effects of graphene oxide nanofluids in machining titanium alloy Ti6Al4V. J Mater Process Technol 271:584–598
Wang G, Li G, Huan Y, Hao C, Chen W (2020) Acrylic acid functionalized graphene oxide: high-efficient removal of cationic dyes from wastewater and exploration on adsorption mechanism. Chemosphere 261:127736
Ibrahim MA, Saleh TA (2020) Partially aminated acrylic acid grafted activated carbon as inexpensive shale hydration inhibitor. Carbohydr Res 491:107960
Naghizadeh A (2015) Comparison between activated carbon and multiwall carbon nanotubes in the removal of cadmium (II) and chromium (VI) from water solutions. J Water Supply Res Technol AQUA 64(1):64–73
Das A, Chakraborty B, Sood AK (2008) Raman spectroscopy of graphene on different substrates and influence of defects. Bull Mater Sci 31(3):579–584
Sharif MZ, Azmi WH, Redhwan AAM, Zawawi NNM, Mamat R (2017) Improvement of nanofluid stability using 4-step UV–Vis spectral absorbency analysis. J Mech Eng SI 4(2):233–247
ASTM E2193-08 (2008) Standard test method for ultraviolet transmittance of monoethylene glycol (ultraviolet spectrophotometric method). ASTM International, West Conshohocken
ASTM E2865-12 (2018) Standard guide for measurement of electrophoretic mobility and zeta potential of nanosized biological materials, ASTM International, West Conshohocken
ASTM D1298-99 (1999) Standard test method for density, relative density (specific gravity), or API gravity of crude petroleum and liquid petroleum products by hydrometer method. ASTM International, West Conshohocken
https://www.engineeringtoolbox.com/water-dynamic-kinematic-viscosity-d_596.html
ASTM Standard D7984-16 (2016) Standard test method for measurement of thermal effusivity of fabrics using a modified transient plane source (MTPS) instrument. ASTM International, West Conshohocken
ASTM D4172-18 (2018) Standard test method for wear preventive characteristics of lubricating fluid (four-ball method). ASTM International, West Conshohocken
Amrita M, Kamesh B, Srikant RR, Prithiviraajan RN, Reddy KS (2019) Thermal enhancement of graphene dispersed emulsifier cutting fluid with different surfactants. Mater Res Express 6(12):125030
Acknowledgements
This work is supported by Science and Engineering Research Board F NO. ECR/2017/001172 as a research project. The authors are grateful to the Science and Engineering Research Board for providing financial support.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no conflict of interest.
Additional information
Technical Editor: Dr. Izabel Fernanda Machado.
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Amrita, M., Srikant, R.R. Quantitative analysis of dispersion, cooling and lubricating properties of graphene dispersed emulsifier oil. J Braz. Soc. Mech. Sci. Eng. 43, 95 (2021). https://doi.org/10.1007/s40430-021-02820-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40430-021-02820-0