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Crystal Structure and Photoluminescence Properties of Two Barium(II) MOFs

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Abstract

In this article, two Ba(II) metal-organic frameworks(MOFs), {[Ba(BPS)(H2O)2]·H2O}n(1) and [Ba(BPS)(H2O)2]n(2)(H2BPS=4,4′-bibenzoic acid-2,2′-sulfone), were synthesized and characterized. X-Ray crystal structural analyses reveal that compounds 1 and 2 have different structures, which is probably related to different coordination modes of ligand in compounds 1 and 2. It is remarkable that compounds 1 and 2 both show excellent thermal stability. The solid-state emission spectra reveal that compounds 1 and 2 both present strong luminescence emission bands at room temperature.

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Authors and Affiliations

  1. Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, School of Materials Science and Engineering, Nankai University, Tianjin, 300350, P. R. China

    Kai Li & Yinghui Zhang

  2. Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), College of Chemistry, Nankai University, Tianjin, 300071, P. R. China

    Kunhuan He, Quanwen Li, Bin Xia & Qinglun Wang

Authors
  1. Kai Li
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  2. Kunhuan He
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  3. Quanwen Li
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  4. Bin Xia
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  5. Qinglun Wang
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  6. Yinghui Zhang
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Corresponding author

Correspondence to Qinglun Wang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21771111, 21601092, 21371104), the “111” Project of China(No.B12015) and the Tianjin Natural Science Foundation, China(Nos.15JCZDJC38800, 16JCZDJC36900).

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Li, K., He, K., Li, Q. et al. Crystal Structure and Photoluminescence Properties of Two Barium(II) MOFs. Chem. Res. Chin. Univ. 34, 700–704 (2018). https://doi.org/10.1007/s40242-018-8054-9

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  • DOI: https://doi.org/10.1007/s40242-018-8054-9

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