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Adsorption Mechanism of Composite Whisker on Copper Ions and Lead Ions

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Abstract

A new kind of inorganic composite adsorbent based on chitin whiskers(CHW) and potassium tetratitanate whiskers(PTW) was synthesized via the thermal deposition to remove Cu2+ and Pb2+ from wastewater. CHW could be successfully coated on the surface of PTW when thermal treated 8 times. The adsorption process was better fitted with the Langmuir and Freundlich models. The adsorption process was more conformed to the Pseudo-second-order model. The results from XPS(X-ray photoelectron spectrum) further show that the adsorption mechanism between CHW-PTW and Cu2+, Pb2+ are both ion exchange and chemical adsorption. Thermodynamic parameters suggest that the adsorption processes are nonspontaneous. The adsorption of Cu2+ and Pb2+ is endothermic and exothermic, respectively.

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Authors and Affiliations

  1. College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China

    Juan Liu, Wenjing Xue, Yongchao Bao & Wanyi Cheng

Authors
  1. Juan Liu
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  2. Wenjing Xue
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  3. Yongchao Bao
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  4. Wanyi Cheng
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Corresponding author

Correspondence to Juan Liu.

Additional information

Supported by the National Natural Science Foundation of China(No.51308314).

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Liu, J., Xue, W., Bao, Y. et al. Adsorption Mechanism of Composite Whisker on Copper Ions and Lead Ions. Chem. Res. Chin. Univ. 34, 792–797 (2018). https://doi.org/10.1007/s40242-018-8015-3

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  • DOI: https://doi.org/10.1007/s40242-018-8015-3

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